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See: Sample Collection Information Document for Pathogens - Companion to Selected Analytical Methods for Environmental Remediation and Recovery (SAM) 2017.
General Notes:
Sample container, holding times, preservation, and sample preparation information has been derived from requirements stated in the SAM 2017 methods, in Section 7.0 of the Sample Collection Information Document (SCID), or best professional judgment. Holding times can be significantly less than 6 months, depending on the specific isotope targeted and its concentration in the sample.
| Analyte: |
1,2-Dichloroethane (degradation product of HD)
|
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| SAM 2017 Method(s) |
NA
|
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| Sample Type: |
Wipes
|
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| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
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| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
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| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
1,2-Dichloroethane (degradation product of HD)
|
|---|
| SAM 2017 Method(s) |
5035A / 8260D (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
5-g coring device or amber VOA vial
AND 1 - 2 oz. glass jar (if needed to determine percent moisture)
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Coring device (If coring device is to be cleaned and reused, samples can be transferred to an amber VOA vial.)
AND glass jar (if needed to determine percent moisture)
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
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| Holding Time: |
14 days if frozen; 48 hours if not frozen
|
|---|
| Preservation: |
Cool to ≤ 6°C; freeze within 48 hours to ≤ negative (-) 7°C [Coring tools should not be frozen below -20°C.]
|
|---|
| Packaging Requirements: |
Wipe outside of coring device or container clean using a damp, then dry cloth. Place the coring device or container in a zipper bag.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Ethylene dichloride, 3, Flammable, 6.1, Poison, UN1184
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
1,2-Dichloroethane (degradation product of HD)
|
|---|
| SAM 2017 Method(s) |
524.2 / 524.3 / 524.4 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw cap VOA vial with fluoropolymer-lined septum, filled with no headspace
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days with acidification; 24 hours if not acidified
|
|---|
| Preservation: |
Prior to collection of treated water samples, add 25 mg ascorbic acid to container for removal of residual chlorine
Method 524.2:
• Adjust to pH < 2 with 1:1 HCl
Methods 524.3 and 524.4:
• Adjust to pH < 2 with maleic acid
For all samples:
• If residual chlorine is > 5 mg/L, add an additional 25 mg ascorbic acid per each 5 mg/L chlorine
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Ethylene dichloride, 3, Flammable, 6.1, Poison, UN1184
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
1,2-Dichloroethane (degradation product of HD)
|
|---|
| SAM 2017 Method(s) |
5030C / 8260D (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Screw cap VOA vial with fluoropolymer-lined septum, filled with no headspace
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days with acidification; 7 days if not acidified
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Adjust to pH < 2 with 1:1 HCl
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Ethylene dichloride, 3, Flammable, 6.1, Poison, UN1184
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
1,2-Dichloroethane (degradation product of HD)
|
|---|
| SAM 2017 Method(s) |
TO-15 (EPA ORD)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
1-L or 6-L canister (depending on suspected concentration)
[Method TO-15 applies to ambient concentrations of VOCs above 0.5 ppbv and typically requires VOC enrichment by concentrating up to 1 L of sample volume; however, when using current technologies, quantifications of approximately 100 pptv have been achieved with 0.5-L sample volumes.]
|
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| Sample Container: |
Specially prepared stainless steel canister
For subatmospheric pressure sampling, the canister is evacuated to 0.05 mm Hg; for pressurized sampling, the sample is collected using a pump and flow control arrangement to achieve a typical 101 - 202 kPa (15 - 30 psig)
|
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| Holding Time: |
30 days
|
|---|
| Preservation: |
None
|
|---|
| Packaging Requirements: |
Ship canister in container provided by laboratory
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Ethylene dichloride, 3, Flammable, 6.1, Poison, UN1184
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
1,3,5-Trinitrobenzene (1,3,5-TNB)
|
|---|
| SAM 2017 Method(s) |
8330B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Trinitrobenzene and trinitrotoluene mixtures, 1.1, Explosive, UN0388
Samples containing secondary explosives at concentrations less than 10% by weight (100,000 mg/kg) or primary explosives at concentrations less than 2% can be sent as normal environmental samples. Consult laboratory on specifics regarding shipping label and shipping requirements for samples with concentrations greater than these amounts.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
1,3,5-Trinitrobenzene (1,3,5-TNB)
|
|---|
| SAM 2017 Method(s) |
3570 / 8290A Appendix A / 8330B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Trinitrobenzene and trinitrotoluene mixtures, 1.1, Explosive, UN0388
Samples containing secondary explosives at concentrations less than 10% by weight (100,000 mg/kg) or primary explosives at concentrations less than 2% can be sent as normal environmental samples. Consult laboratory on specifics regarding shipping label and shipping requirements for samples with concentrations greater than these amounts.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
1,3,5-Trinitrobenzene (1,3,5-TNB)
|
|---|
| SAM 2017 Method(s) |
3535A / 8330B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Trinitrobenzene and trinitrotoluene mixtures, 1.1, Explosive, UN0388
Samples containing secondary explosives at concentrations less than 10% by weight (100,000 mg/kg) or primary explosives at concentrations less than 2% can be sent as normal environmental samples. Consult laboratory on specifics regarding shipping label and shipping requirements for samples with concentrations greater than these amounts.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
1,3,5-Trinitrobenzene (1,3,5-TNB)
|
|---|
| SAM 2017 Method(s) |
3535A / 8330B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Trinitrobenzene and trinitrotoluene mixtures, 1.1, Explosive, UN0388
Samples containing secondary explosives at concentrations less than 10% by weight (100,000 mg/kg) or primary explosives at concentrations less than 2% can be sent as normal environmental samples. Consult laboratory on specifics regarding shipping label and shipping requirements for samples with concentrations greater than these amounts.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
1,3,5-Trinitrobenzene (1,3,5-TNB)
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
1,4-Dithiane (degradation product of HD)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
1,4-Dithiane (degradation product of HD)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
• Cool to ≤ 6°C; keep from freezing
For treated water samples:
Preservatives/dechlorinating agents not required, but the analyte is not affected by the following, if added to address other analytes:
• Sodium sulfite
• 1.6 - 2.0 mg NH4Cl
[Sodium sulfite can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: for a 1-L sample, add 40 - 50 mg sodium sulfite (1.6 - 2 mg/40-mL sample).]
For all other samples:
• Adjust pH < 2 with 1:1 HCl
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
1,4-Dithiane (degradation product of HD)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
• Cool to ≤ 6°C; keep from freezing
For treated water samples:
Preservatives/dechlorinating agents not required, but the analyte is not affected by the following, if added to address other analytes:
• Sodium sulfite
• 1.6 - 2.0 mg NH4Cl
[Sodium sulfite can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: for a 1-L sample, add 40 - 50 mg sodium sulfite (1.6 - 2 mg/40-mL sample).]
For all other samples:
• Adjust pH < 2 with 1:1 HCl
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
1,4-Dithiane (degradation product of HD)
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
1,4-Dithiane (degradation product of HD)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
1,4-Thioxane (degradation product of HD)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
• Cool to ≤ 6°C; keep from freezing
For treated water samples:
• Add sodium sulfite to remove residual chlorine OR
• Add 1.6 - 2.0 mg NH4Cl
[Sodium sulfite can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: for a 1-L sample, add 40 - 50 mg sodium sulfite (1.6 - 2 mg/40-mL sample).]
For all other samples:
• Adjust to pH < 2 with 1:1 HCl
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Flammable Liquids, n.o.s, 3, Flammable, UN1993
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
1,4-Thioxane (degradation product of HD)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
• Cool to ≤ 6°C; keep from freezing
For treated water samples:
• Add sodium sulfite to remove residual chlorine OR
• Add 1.6 - 2.0 mg NH4Cl
[Sodium sulfite can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: for a 1-L sample, add 40 - 50 mg sodium sulfite (1.6 - 2 mg/40-mL sample).]
For all other samples:
• Adjust to pH < 2 with 1:1 HCl
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Flammable Liquids, n.o.s, 3, Flammable, UN1993
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
1,4-Thioxane (degradation product of HD)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Flammable Solid, n.o.s, 3, Flammable, UN1325
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
1,4-Thioxane (degradation product of HD)
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
1,4-Thioxane (degradation product of HD)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Flammable Solid, n.o.s, 3, Flammable, UN1325
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
1-Methylethyl ester ethylphosphonofluoridic acid (GE)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/115 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Cool to ≤ 6°C; keep from freezing
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
1-Methylethyl ester ethylphosphonofluoridic acid (GE)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/115 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Cool to ≤ 6°C; keep from freezing
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
1-Methylethyl ester ethylphosphonofluoridic acid (GE)
|
|---|
| SAM 2017 Method(s) |
TO-17 (EPA ORD)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
1 - 4 L (flow rate = 16 - 67 mL/min)
|
|---|
| Sample Container: |
Stainless steel, 3.5-inch long tubes with a 6-cm sorbent bed and 1/4-inch o.d.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wrap tube in aluminum foil, and place in a clean sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
1-Methylethyl ester ethylphosphonofluoridic acid (GE)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/115 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap containers with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
1-Methylethyl ester ethylphosphonofluoridic acid (GE)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/115 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap containers with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
2,4,6-Trinitrotoluene (2,4,6-TNT)
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
2,4,6-Trinitrotoluene (2,4,6-TNT)
|
|---|
| SAM 2017 Method(s) |
8330B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Trinitrobenzene and trinitrotoluene mixtures, 1.1, Explosive, UN0388
Samples containing secondary explosives at concentrations less than 10% by weight (100,000 mg/kg) or primary explosives at concentrations less than 2% can be sent as normal environmental samples. Consult laboratory on specifics regarding shipping label and shipping requirements for samples with concentrations greater than these amounts.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
2,4,6-Trinitrotoluene (2,4,6-TNT)
|
|---|
| SAM 2017 Method(s) |
3535A / 8330B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Trinitrobenzene and trinitrotoluene mixtures, 1.1, Explosive, UN0388
Samples containing secondary explosives at concentrations less than 10% by weight (100,000 mg/kg) or primary explosives at concentrations less than 2% can be sent as normal environmental samples. Consult laboratory on specifics regarding shipping label and shipping requirements for samples with concentrations greater than these amounts.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
2,4,6-Trinitrotoluene (2,4,6-TNT)
|
|---|
| SAM 2017 Method(s) |
3535A / 8330B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Trinitrobenzene and trinitrotoluene mixtures, 1.1, Explosive, UN0388
Samples containing secondary explosives at concentrations less than 10% by weight (100,000 mg/kg) or primary explosives at concentrations less than 2% can be sent as normal environmental samples. Consult laboratory on specifics regarding shipping label and shipping requirements for samples with concentrations greater than these amounts.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
2,4,6-Trinitrotoluene (2,4,6-TNT)
|
|---|
| SAM 2017 Method(s) |
3570 / 8290A Appendix A / 8330B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Trinitrobenzene and trinitrotoluene mixtures, 1.1, Explosive, UN0388
Samples containing secondary explosives at concentrations less than 10% by weight (100,000 mg/kg) or primary explosives at concentrations less than 2% can be sent as normal environmental samples. Consult laboratory on specifics regarding shipping label and shipping requirements for samples with concentrations greater than these amounts.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
2-Chloroethanol
|
|---|
| SAM 2017 Method(s) |
5030C / 8260D (EPA SW-846)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw cap VOA vial with fluoropolymer-lined septum, filled with no headspace
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days with acidification; 7 days if not acidified
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Adjust to pH < 2 with 1:1 HCl
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Ethylene chlorohydrin, 3, Flammable liquid, 6.1 Poison, UN1135
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
2-Chloroethanol
|
|---|
| SAM 2017 Method(s) |
2513 (NIOSH)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
2 (at 5 ppm) - 35 L (flow rate = 0.01 - 0.2 L/min)
|
|---|
| Sample Container: |
Solid sorbent tube (petroleum charcoal [100 mg/50 mg])
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of sorbent tube clean using a damp, then dry cloth. Cap tubes with plastic (not rubber) caps. Place tubes in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Ethylene chlorohydrin, 3, Flammable liquid, 6.1 Poison, UN1135
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
2-Chloroethanol
|
|---|
| SAM 2017 Method(s) |
5030C / 8260D (EPA SW-846)
[Tier II]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw cap VOA vial with fluoropolymer-lined septum, filled with no headspace
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days with acidification; 7 days if not acidified
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Adjust to pH < 2 with 1:1 HCl
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Ethylene chlorohydrin, 3, Flammable liquid, 6.1 Poison, UN1135
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
2-Chloroethanol
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
2-Chloroethanol
|
|---|
| SAM 2017 Method(s) |
5035A / 8260D (EPA SW-846)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
5-g coring device or amber VOA vial
AND 1 - 2 oz. glass jar (if needed to determine percent moisture)
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Coring device (If coring device is to be cleaned and reused, samples can be transferred to an amber VOA vial.)
AND glass jar (if needed to determine percent moisture)
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days if frozen; 48 hours if not frozen
|
|---|
| Preservation: |
Cool to ≤ 6°C; freeze within 48 hours to ≤ negative (-) 7°C [Coring tools should not be frozen below -20°C.]
|
|---|
| Packaging Requirements: |
Wipe outside of coring device or container clean using a damp, then dry cloth. Place the coring device or container in a zipper bag.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Ethylene chlorohydrin, 3, Flammable liquid, 6.1 Poison, UN1135
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
2-Chlorovinyl arsonic acid (CVAOA) (degradation product of Lewisite)
|
|---|
| SAM 2017 Method(s) |
IO-3.1 / IO-3.4/IO-3.5 (EPA ORD)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
Up to 1700 m3
|
|---|
| Sample Container: |
Filter (quartz, silica, or cellulose fiber)
|
|---|
| Holding Time: |
6 months
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Place filter in protective covering. Place protected filter in double plastic bags, and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
2-Chlorovinyl arsonic acid (CVAOA) (degradation product of Lewisite)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-15/258 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or
1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
VOA vial with fluoropolymer-lined cap
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap containers with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
2-Chlorovinyl arsonic acid (CVAOA) (degradation product of Lewisite)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-15/258 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
VOA vial with fluoropolymer-lined cap
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap containers with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
2-Chlorovinyl arsonic acid (CVAOA) (degradation product of Lewisite)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-15/258 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
VOA vial with fluoropolymer-lined cap
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
2-Chlorovinyl arsonic acid (CVAOA) (degradation product of Lewisite)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-15/258 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
VOA vial with fluoropolymer-lined cap
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
2-Chlorovinylarsonous acid (2-CVAA) (degradation product of Lewisite)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-15/258 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
VOA vial with fluoropolymer-lined cap
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap containers with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
2-Chlorovinylarsonous acid (2-CVAA) (degradation product of Lewisite)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-15/258 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
VOA vial with fluoropolymer-lined cap
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap containers with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
2-Chlorovinylarsonous acid (2-CVAA) (degradation product of Lewisite)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-15/258 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
VOA vial with fluoropolymer-lined cap
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
2-Chlorovinylarsonous acid (2-CVAA) (degradation product of Lewisite)
|
|---|
| SAM 2017 Method(s) |
IO-3.1 / IO-3.4/IO-3.5 (EPA ORD)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
Up to 1700 m3
|
|---|
| Sample Container: |
Filter (quartz, silica, or cellulose fiber)
|
|---|
| Holding Time: |
6 months
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Place filter in protective covering. Place protected filter in double plastic bags, and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
2-Chlorovinylarsonous acid (2-CVAA) (degradation product of Lewisite)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-15/258 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
VOA vial with fluoropolymer-lined cap
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
2-Fluoroethanol
|
|---|
| SAM 2017 Method(s) |
2513 (NIOSH)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
2 (at 5 ppm) - 35 L (flow rate = 0.01 - 0.2 L/min)
|
|---|
| Sample Container: |
Solid sorbent tube (petroleum charcoal [100 mg/50 mg])
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of sorbent tube clean using a damp, then dry cloth. Cap tubes with plastic (not rubber) caps. Place tubes in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
2-Fluoroethanol
|
|---|
| SAM 2017 Method(s) |
5030C / 8260D (SW-846)
[Tier III]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw cap VOA vial with fluoropolymer-lined septum, filled with no headspace
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days with acidification; 7 days if not acidified
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Adjust to pH < 2 with 1:1 HCl
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film, and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
2-Fluoroethanol
|
|---|
| SAM 2017 Method(s) |
5030C / 8260D (SW-846)
[Tier III]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw cap VOA vial with fluoropolymer-lined septum, filled with no headspace
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days with acidification; 7 days if not acidified
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Adjust to pH < 2 with 1:1 HCl
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film, and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
2-Fluoroethanol
|
|---|
| SAM 2017 Method(s) |
5035A / 8260D (EPA SW-846)
[Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
5-g coring device or amber VOA vial
AND 1 - 2 oz. glass jar (if needed to determine percent moisture)
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Coring device (If coring device is to be cleaned and reused, samples can be transferred to an amber VOA vial.)
AND glass jar (if needed to determine percent moisture)
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days if frozen;
48 hours if not frozen
|
|---|
| Preservation: |
Cool to ≤ 6°C; freeze within 48 hours to ≤ negative (-) 7°C [Coring tools should not be frozen below -20°C.]
|
|---|
| Packaging Requirements: |
Wipe outside of coring device or container clean using a damp, then dry cloth. Place the coring device or container in a zipper bag.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
2-Fluoroethanol
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
3-Chloro-1,2-propanediol
|
|---|
| SAM 2017 Method(s) |
Eur. J. Lipid Sci. Technol. (2011) 113:345-355
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Glycerol alpha-monochlorohydrin, 6.1, Toxic substance, UN2689
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
3-Chloro-1,2-propanediol
|
|---|
| SAM 2017 Method(s) |
J. Chromatogr. A (2000) 866: 65-77
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
15 days
|
|---|
| Preservation: |
• Adjust pH to 3 - 8 with sodium sulfite or 1:1 HCl
• Cool to ≤°6; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Glycerol alpha-monochlorohydrin, 6.1, Toxic substance, UN2689
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
3-Chloro-1,2-propanediol
|
|---|
| SAM 2017 Method(s) |
J. Chromatogr. A (2000) 866: 65-77
[Tier II]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
15 days
|
|---|
| Preservation: |
• Adjust pH to 3 - 8 with sodium sulfite or 1:1 HCl
• Cool to ≤°6; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Glycerol alpha-monochlorohydrin, 6.1, Toxic substance, UN2689
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
3-Chloro-1,2-propanediol
|
|---|
| SAM 2017 Method(s) |
TO-10A (EPA ORD)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
240 - 7200 L (flow rate = 1 - 5 L/min)
|
|---|
| Sample Container: |
Sorbent cartridge containing PUF or PUF in combination with other solid sorbent
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Remove PUF cartridge from sampler, wrap with aluminum foil used to store cartridge, and place in a sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Glycerol alpha-monochlorohydrin, 6.1, Toxic substance, UN2689
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
3-Chloro-1,2-propanediol
|
|---|
| SAM 2017 Method(s) |
Eur. J. Lipid Sci. Technol. (2011) 113:345-355
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Glycerol alpha-monochlorohydrin, 6.1, Toxic substance, UN2689
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
3-Methyl fentanyl
|
|---|
| SAM 2017 Method(s) |
3541 / 3545A (EPA SW-846) / J. Chromatogr. B (2014) 962: 52-58
[Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organic, n.o.s., solid, 6.1, Poison, UN2811
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
3-Methyl fentanyl
|
|---|
| SAM 2017 Method(s) |
3520C / 3535A (EPA SW-846) / J. Chromatogr. B (2014) 962: 52-58
[Tier III]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organic, n.o.s., liquid, 6.1, Poison, UN2810
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
3-Methyl fentanyl
|
|---|
| SAM 2017 Method(s) |
3520C / 3535A (EPA SW-846) / J. Chromatogr. B (2014) 962: 52-58
[Tier III]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organic, n.o.s., liquid, 6.1, Poison, UN2810
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
3-Methyl fentanyl
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
3-Methyl fentanyl
|
|---|
| SAM 2017 Method(s) |
3570 / 8290A (EPA SW-846) / J. Chromatogr. B (2014) 962: 52-58
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organic, n.o.s., solid, 6.1, Poison, UN2811
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
4-Aminopyridine
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
4-Aminopyridine
|
|---|
| SAM 2017 Method(s) |
3535A / 8330B (EPA SW-846)
[Tier III]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Aminopyridines, 6.1, Poison, UN2671
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
4-Aminopyridine
|
|---|
| SAM 2017 Method(s) |
3570 / 8290A Appendix A / 8330B (EPA SW-846)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Aminopyridines, 6.1, Poison, UN2671
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
4-Aminopyridine
|
|---|
| SAM 2017 Method(s) |
8330B (EPA SW-846)
[Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Aminopyridines, 6.1, Poison, UN2671
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
4-Aminopyridine
|
|---|
| SAM 2017 Method(s) |
3535A / 8330B (EPA SW-846)
[Tier III]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Aminopyridines, 6.1, Poison, UN2671
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Acephate
|
|---|
| SAM 2017 Method(s) |
J. Chromatogr. A (2007) 1154(1): 3-25
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
TBD
|
|---|
| Sample Container: |
TBD
|
|---|
| Holding Time: |
Until holding time data are available, analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Acephate
|
|---|
| SAM 2017 Method(s) |
Chromatographia, 63(5/6): 223-237
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Acephate
|
|---|
| SAM 2017 Method(s) |
J. Chromatogr. A (2007) 1154(1): 3-25
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth glass or fluoropolymer container with fluoropolymer-lined lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
Until holding time data are available, analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Acephate
|
|---|
| SAM 2017 Method(s) |
J. Chromatogr. A (2007) 1154(1): 3-25
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth glass or fluoropolymer container with fluoropolymer-lined lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
Until holding time data are available, analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Acephate
|
|---|
| SAM 2017 Method(s) |
538
(EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
• Prior to collection, add 400 µL of ammonium acetate concentrated stock and 80 µL of concentrated sodium omadine stock to sample container [Concentrations of ammonium acetate and sodium omadine in the sample should be 1.5 g/L and 64 mg/L, respectively.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Acrylamide
|
|---|
| SAM 2017 Method(s) |
PV2004 (OSHA)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
120 L (flow rate = 1 L/min)
|
|---|
| Sample Container: |
Filter/solid sorbent tube (13mm quartz fiber filter)
• OVS-7 tube (XAD-7 resin)
• OVS-2 (XAD-2 resin)
• OVS-SG (silica gel)
|
|---|
| Holding Time: |
13 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of sorbent tube clean using a damp, then dry cloth. Cap both ends of the tube with plastic caps. Place tube in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Acrylamide, solid, 6.1, Poison, UN2074
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Acrylamide
|
|---|
| SAM 2017 Method(s) |
8316 (EPA SW-846)
[Tier II]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the bottle with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Acrylamide solution, 6.1, Poison, UN3426
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Acrylamide
|
|---|
| SAM 2017 Method(s) |
Water Extraction /
8316 (EPA SW-846)
[Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the bottle with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Acrylamide, solid, 6.1, Poison, UN2074
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Acrylamide
|
|---|
| SAM 2017 Method(s) |
3570 / 8290A Appendix A / 8316 (EPA SW-846)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Acrylamide, solid, 6.1, Poison, UN2074
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Acrylamide
|
|---|
| SAM 2017 Method(s) |
8316 (EPA SW-846)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the bottle with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Acrylamide solution, 6.1, Poison, UN3426
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Acrylonitrile
|
|---|
| SAM 2017 Method(s) |
5035A / 8260D (EPA SW-846)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
5-g coring device or amber VOA vial
AND 1 - 2 oz. glass jar (if needed to determine percent moisture)
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Coring device (If coring device is to be cleaned and reused, samples can be transferred to an amber VOA vial.)
AND glass jar (if needed to determine percent moisture)
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days if frozen; 48 hours if not frozen
|
|---|
| Preservation: |
Cool to ≤6°C; freeze within 48 hours to ≤ negative (-) 7°C [Coring tools should not be frozen below -20°C.]
|
|---|
| Packaging Requirements: |
Wipe outside of coring device or container clean using a damp, then dry cloth. Place the coring device or container in a zipper bag.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Acrylonitrile, stabilized, 3, Flammable liquid, 6.1, Poison, UN1093
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Acrylonitrile
|
|---|
| SAM 2017 Method(s) |
3570 / 8290A Appendix A / 8260D (EPA SW-846)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Acrylonitrile, stabilized, 3, Flammable liquid, 6.1, Poison, UN1093
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Acrylonitrile
|
|---|
| SAM 2017 Method(s) |
524.2 / 524.3 / 524.4
(EPA OW)
[Tier II]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw cap VOA vial with fluoropolymer-lined septum, filled with no headspace
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days with acidification; 24 hours if not acidified
|
|---|
| Preservation: |
Prior to collection of treated water samples, add 25 mg ascorbic acid to container for removal of residual chlorine
Method 524.2:
• Adjust to pH < 2 with 1:1 HCl
Methods 524.3 and 524.4:
• Adjust to pH < 2 with maleic acid
For all samples:
• If residual chlorine is > 5 mg/L, add an additional 25 mg ascorbic acid per each 5 mg/L chlorine
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Acrylonitrile, stabilized, 3, Flammable liquid, 6.1, Poison, UN1093
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Acrylonitrile
|
|---|
| SAM 2017 Method(s) |
524.2 / 524.3 / 524.4 (EPA OW)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw cap VOA vial with fluoropolymer-lined septum, filled with no headspace
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days with acidification; 24 hours if not acidified
|
|---|
| Preservation: |
Prior to collection of treated water samples, add 25 mg ascorbic acid to container for removal of residual chlorine
Method 524.2:
• Adjust to pH < 2 with 1:1 HCl
Methods 524.3 and 524.4:
• Adjust to pH < 2 with maleic acid
For all samples:
• If residual chlorine is > 5 mg/L, add an additional 25 mg ascorbic acid per each 5 mg/L chlorine
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Acrylonitrile, stabilized, 3, Flammable liquid, 6.1, Poison, UN1093
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Acrylonitrile
|
|---|
| SAM 2017 Method(s) |
PV2004 (OSHA)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
120 L (flow rate = 1 L/min)
|
|---|
| Sample Container: |
Filter/solid sorbent tube (13mm quartz fiber filter)
• OVS-7 tube (XAD-7 resin)
• OVS-2 (XAD-2 resin)
• OVS-SG (silica gel)
|
|---|
| Holding Time: |
13 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of sorbent tube clean using a damp, then dry cloth. Cap both ends of the tube with plastic caps. Place tube in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Acrylonitrile, stabilized, 3, Flammable liquid, 6.1, Poison, UN1093
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Aldicarb (Temik)
|
|---|
| SAM 2017 Method(s) |
5601 (NIOSH)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
240 - 480 L (flow rate = 0.1 - 1 L/min)
|
|---|
| Sample Container: |
Filter/solid sorbent tube (OVS-2 tube: 13 mm quartz fiber filter, XAD-2 [270 mg/140 mg])
|
|---|
| Holding Time: |
30 days if frozen; 7 days at room temperature (24°C)
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of sorbent tube clean using a damp, then dry cloth. Cap both ends of the tube with plastic caps. Place tube in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Carbamate pesticides, solid, toxic, 6.1, UN2757
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Aldicarb (Temik)
|
|---|
| SAM 2017 Method(s) |
3570 / 8290A Appendix A / 8318A (EPA SW-846)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Carbamate pesticides, solid, toxic, 6.1, UN2757
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Aldicarb (Temik)
|
|---|
| SAM 2017 Method(s) |
D7645-16 (ASTM)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
• Acidify to pH ≤ 3.8 with glacial acetic acid
• Cool to ≤ 6°C; keep from freezing
• Prior to collection of treated water samples, add 10 mg ascorbic acid to sample container
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Carbamate pesticides, liquid, toxic, 6.1, Poison, UN2992
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Aldicarb (Temik)
|
|---|
| SAM 2017 Method(s) |
531.2 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
28 days
|
|---|
| Preservation: |
• Prior to collection, add 0.4 g potassium dihydrogen citrate and 3.2 - 4.8 mg sodium thiosulfate to sample container
• Agitate for 1 minute after collection
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Carbamate pesticides, liquid, toxic, 6.1, Poison, UN2992
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Aldicarb (Temik)
|
|---|
| SAM 2017 Method(s) |
8318A (EPA SW-846)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Carbamate pesticides, solid, toxic, 6.1, UN2757
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Aldicarb sulfone
|
|---|
| SAM 2017 Method(s) |
8318A (EPA SW-846)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Carbamate pesticides, solid, toxic, 6.1, UN2757
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Aldicarb sulfone
|
|---|
| SAM 2017 Method(s) |
3570 / 8290A Appendix A / 8318A (EPA SW-846)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Carbamate pesticides, solid, toxic, 6.1, UN2757
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Aldicarb sulfone
|
|---|
| SAM 2017 Method(s) |
531.2 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
28 days
|
|---|
| Preservation: |
• Prior to collection, add 0.4 g potassium dihydrogen citrate and 3.2 - 4.8 mg sodium thiosulfate to sample container
• Agitate for 1 minute after collection
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Carbamate pesticides, liquid, toxic, 6.1, Poison, UN2992
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Aldicarb sulfone
|
|---|
| SAM 2017 Method(s) |
D7645-16 (ASTM)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
• Acidify to pH ≤ 3.8 with glacial acetic acid
• Cool to ≤ 6°C; keep from freezing
• Prior to collection of treated water samples, add 10 mg ascorbic acid to sample container
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Carbamate pesticides, liquid, toxic, 6.1, Poison, UN2992
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Aldicarb sulfone
|
|---|
| SAM 2017 Method(s) |
5601 (NIOSH)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
240 - 480 L (flow rate = 0.1 - 1 L/min)
|
|---|
| Sample Container: |
Filter/solid sorbent tube (OVS-2 tube: 13 mm quartz filter, XAD-2, [270 mg/140 mg])
|
|---|
| Holding Time: |
30 days if frozen; 7 days at room temperature (24°C)
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of sorbent tube clean using a damp, then dry cloth. Cap both ends of the tube with plastic caps. Place tube in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Carbamate pesticides, solid, toxic, 6.1, UN2757
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Aldicarb sulfoxide
|
|---|
| SAM 2017 Method(s) |
8318A (EPA SW-846)
[Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Carbamate pesticides, solid, toxic, 6.1, UN2757
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Aldicarb sulfoxide
|
|---|
| SAM 2017 Method(s) |
531.2 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
28 days
|
|---|
| Preservation: |
• Prior to sample collection, add 0.4 g potassium dihydrogen citrate and 3.2 - 4.8 mg sodium thiosulfate to sample container
• Agitate for 1 minute after collection
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Carbamate pesticides, liquid, toxic, 6.1, Poison, UN2992
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Aldicarb sulfoxide
|
|---|
| SAM 2017 Method(s) |
3570 / 8290A Appendix A / 8318A (EPA SW-846)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Carbamate pesticides, solid, toxic, 6.1, UN2757
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Aldicarb sulfoxide
|
|---|
| SAM 2017 Method(s) |
D7645-16 (ASTM)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
• Acidify to pH ≤ 3.8 with glacial acetic acid
• Cool to ≤ 6°C; keep from freezing
• Prior to collection of treated water samples, add 10 mg ascorbic acid to sample container
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Carbamate pesticides, liquid, toxic, 6.1, Poison, UN2992
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Aldicarb sulfoxide
|
|---|
| SAM 2017 Method(s) |
5601 (NIOSH)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
240 - 480 L (flow rate = 0.1 - 1 L/min)
|
|---|
| Sample Container: |
Filter/solid sorbent tube (OVS-2 tube: 13 mm quartz filter, XAD-2, [270 mg/140 mg])
|
|---|
| Holding Time: |
30 days if frozen; 7 days at room temperature (24°C)
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of sorbent tube clean using a damp, then dry cloth. Cap both ends of the tube with plastic caps. Place tube in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Carbamate pesticides, solid, toxic, 6.1, UN2757
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Allyl alcohol
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Allyl alcohol
|
|---|
| SAM 2017 Method(s) |
5030C / 8260D (EPA SW-846)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw cap VOA vial with fluoropolymer-lined septum, filled with no headspace
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days with acidification; 7 days if not acidified
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Adjust to pH < 2 with 1:1 HCl
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap glass bottles with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Allyl alcohol, 3, Flammable liquid, 6.1, Poison, UN1098
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Allyl alcohol
|
|---|
| SAM 2017 Method(s) |
5030C / 8260D (EPA SW-846)
[Tier II]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw cap VOA vial with fluoropolymer-lined septum, filled with no headspace
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days with acidification; 7 days if not acidified
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Adjust to pH < 2 with 1:1 HCl
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap glass bottles with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Allyl alcohol, 3, Flammable liquid, 6.1, Poison, UN1098
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Allyl alcohol
|
|---|
| SAM 2017 Method(s) |
TO-15 (EPA ORD)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
1-L or 6-L canister (depending on suspected concentration)
[Method TO-15 applies to ambient concentrations of VOCs above 0.5 ppbv and typically requires VOC enrichment by concentrating up to 1 L of sample volume; however, when using current technologies, quantifications of approximately 100 pptv have been achieved with 0.5-L sample volumes.]
|
|---|
| Sample Container: |
Specially prepared stainless steel canister
For subatmospheric pressure sampling, the canister is evacuated to 0.05 mm Hg; for pressurized sampling, the sample is collected using a pump and flow control arrangement to achieve a typical 101 - 202 kPa (15 - 30 psig)
|
|---|
| Holding Time: |
30 days
|
|---|
| Preservation: |
None
|
|---|
| Packaging Requirements: |
Ship canister in container provided by laboratory.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Allyl alcohol, 3, Flammable liquid, 6.1, Poison, UN1098
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Allyl alcohol
|
|---|
| SAM 2017 Method(s) |
5035A / 8260D (EPA SW-846)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
5-g coring device or amber VOA vial
AND 1 - 2 oz. glass jar (if needed to determine percent moisture)
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Coring device (If coring device is to be cleaned and reused, samples can be transferred to an amber VOA vial.)
AND glass jar (if needed to determine percent moisture)
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days if frozen; 48 hours if not frozen
|
|---|
| Preservation: |
Cool to ≤6°C; freeze within 48 hours to ≤ negative (-) 7°C [Coring tools should not be frozen below -20 °C.]
|
|---|
| Packaging Requirements: |
Wipe outside of coring device or container clean using a damp, then dry cloth. Place the coring device or container in a zipper bag.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Allyl alcohol, 3, Flammable liquid, 6.1, Poison, UN1098
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Ammonia
|
|---|
| SAM 2017 Method(s) |
4500- NH3 B / 4500- NH3 G (SM)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
500 mL
|
|---|
| Sample Container: |
Polyethylene or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
28 days with acidification; analyze immediately / as soon as possible if not acidified
|
|---|
| Preservation: |
• Cool to ≤ 6°C or acidify to pH < 2; keep from freezing
• Add sodium thiosulfate to remove residual chlorine from treated water samples (Can be added in the field or upon receipt in the laboratory.) [Sodium thiosulfate can be added either prior to or after sample collection. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND (if greater than 10% ammonia by volume) Ammonia solution, 8, Corrosive, UN2672
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Ammonia
|
|---|
| SAM 2017 Method(s) |
6015 (NIOSH)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
0.1 (at 50 ppm) - 96 L (flow rate = 0.1 - 0.2 L/min)
|
|---|
| Sample Container: |
Solid sorbent tube (sulfuric acid-treated silica gel)
|
|---|
| Holding Time: |
Until holding time data are available, analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of sorbent tube clean using a damp, then dry cloth. Cap tube with plastic (not rubber) caps immediately after sampling. Place tubes in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND (if greater than 10% ammonia by volume) Ammonia solution, 8, Corrosive, UN2672
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Ammonia
|
|---|
| SAM 2017 Method(s) |
350.1 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
500 mL
|
|---|
| Sample Container: |
Polyethylene or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
28 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples (Can be added in the field or upon receipt in the laboratory.) [Sodium thiosulfate can be added either prior to or after sample collection. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Adjust to pH < 2 with H2SO4
• Cool to≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND (if greater than 10% ammonia by volume) Ammonia solution, 8, Corrosive, UN2672
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Ammonia
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Ammonia
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Ammonium metavanadate (analyze as total vanadium)
|
|---|
| SAM 2017 Method(s) |
3015A / 6010D/ 6020B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
125 mL
|
|---|
| Sample Container: |
Fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
6 months with acidification. Samples must be acidified within 14 days of collection.
|
|---|
| Preservation: |
• Acidify to pH < 2 with HNO3
• Cool to ≤ 6°C; keep from freezing
If sample collectors are not able to preserve samples in the field (e.g., acid preservatives are not available), the samples may be preserved in the laboratory. If preserved in the laboratory, however, samples must be held for at least 24 hours prior to analysis.
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Ammonium metavanadate, 6.1, Poison, UN2859
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Ammonium metavanadate (analyze as total vanadium)
|
|---|
| SAM 2017 Method(s) |
IO-3.1 / IO-3.4 / IO-3.5 (EPA ORD)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
Up to 1700 m3
|
|---|
| Sample Container: |
Filter (quartz, silica, or cellulose fiber)
|
|---|
| Holding Time: |
6 months
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Place filter in protective covering. Place protected filter in double plastic bags, and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Ammonium metavanadate, 6.1, Poison, UN2859
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Ammonium metavanadate (analyze as total vanadium)
|
|---|
| SAM 2017 Method(s) |
200.7 / 200.8 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
125 mL
|
|---|
| Sample Container: |
Fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
6 months with acidification. Samples must be acidified within 14 days of collection.
|
|---|
| Preservation: |
• Acidify to pH < 2 with HNO3
• Cool to ≤ 6°C; keep from freezing
If sample collectors are not able to preserve samples in the field (e.g., acid preservatives are not available), the samples may be preserved in the laboratory. If preserved in the laboratory, however, samples must be held for at least 24 hours prior to analysis.
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Ammonium metavanadate, 6.1, Poison, UN2859
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Ammonium metavanadate (analyze as total vanadium)
|
|---|
| SAM 2017 Method(s) |
3050B / 3051A / 6010D / 6020B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
Analyze immediately / as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Ammonium metavanadate, 6.1, Poison, UN2859
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Ammonium metavanadate (analyze as total vanadium)
|
|---|
| SAM 2017 Method(s) |
9102 (NIOSH) / 6010D / 6020B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
Analyze immediately / as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Ammonium metavanadate, 6.1, Poison, UN2859
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Arsenic trioxide (analyze as total arsenic)
|
|---|
| SAM 2017 Method(s) |
3050B / 3051A / 6010D / 6020B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
Analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Arsenic trioxide, 6.1, Poison, UN1561
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Arsenic trioxide (analyze as total arsenic)
|
|---|
| SAM 2017 Method(s) |
9102 (NIOSH) / 6010D / 6020B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
Analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Arsenic trioxide, 6.1, Poison, UN1561
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Arsenic trioxide (analyze as total arsenic)
|
|---|
| SAM 2017 Method(s) |
IO-3.1 / IO-3.4 / IO-3.5 (EPA ORD)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
Up to 1700 m3
|
|---|
| Sample Container: |
Filter (quartz, silica, or cellulose fiber)
|
|---|
| Holding Time: |
6 months
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Place filter in protective covering. Place protected filter in double plastic bags, and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Arsenic trioxide, 6.1, Poison, UN1561
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Arsenic trioxide (analyze as total arsenic)
|
|---|
| SAM 2017 Method(s) |
3015A / 6010D / 6020B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
125 mL
|
|---|
| Sample Container: |
Fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
6 months with acidification. Samples must be acidified within 14 days of collection.
|
|---|
| Preservation: |
• Acidify to pH < 2 with HNO3 [If arsenic species are to be determined, remove unpreserved aliquot prior to sample preservation.]
• Cool to ≤ 6°C; keep from freezing
If sample collectors are not able to preserve samples in the field (e.g., acid preservatives are not available), the samples may be preserved in the laboratory. If preserved in the laboratory, however, samples must be held for at least 24 hours prior to analysis.
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Arsenic trioxide, 6.1, Poison, UN1561
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Arsenic trioxide (analyze as total arsenic)
|
|---|
| SAM 2017 Method(s) |
200.7 / 200.8 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
125 mL
|
|---|
| Sample Container: |
Fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
6 months with acidification. Samples must be acidified within 14 days of collection.
|
|---|
| Preservation: |
• Acidify to pH < 2 with HNO3 [If arsenic species are to be determined, remove unpreserved aliquot prior to sample preservation.]
• Cool to ≤ 6°C; keep from freezing
If sample collectors are not able to preserve samples in the field (e.g., acid preservatives are not available), the samples may be preserved in the laboratory. If preserved in the laboratory, however, samples must be held for at least 24 hours prior to analysis.
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Arsenic trioxide, 6.1, Poison, UN1561
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Arsenic, Total
|
|---|
| SAM 2017 Method(s) |
3015A / 6010D / 6020B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
125 mL
|
|---|
| Sample Container: |
Fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
6 months with acidification. Samples must be acidified within 14 days of collection.
|
|---|
| Preservation: |
• Acidify to pH < 2 with HNO3 [If arsenic species are to be determined, remove unpreserved aliquot prior to sample preservation.]
• Cool to ≤ 6°C; keep from freezing
If sample collectors are not able to preserve samples in the field (e.g., acid preservatives are not available), the samples may be preserved in the laboratory. If preserved in the laboratory, however, samples must be held for at least 24 hours prior to analysis.
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Arsenic, 6.1, Poison, UN1558
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Arsenic, Total
|
|---|
| SAM 2017 Method(s) |
IO-3.1 / IO-3.4 / IO-3.5(EPA ORD)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
Up to 1700 m3
|
|---|
| Sample Container: |
Filter (quartz, silica, or cellulose fiber)
|
|---|
| Holding Time: |
6 months
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Place filter in protective covering. Place protected filter in double plastic bags, and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Arsenic, 6.1, Poison, UN1558
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Arsenic, Total
|
|---|
| SAM 2017 Method(s) |
200.7 / 200.8 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
125 mL
|
|---|
| Sample Container: |
Fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
6 months with acidification. Samples must be acidified within 14 days of collection.
|
|---|
| Preservation: |
• Acidify to pH < 2 with HNO3 [If arsenic species are to be determined, remove unpreserved aliquot prior to sample preservation.]
• Cool to ≤ 6°C; keep from freezing
If sample collectors are not able to preserve samples in the field (e.g., acid preservatives are not available), the samples may be preserved in the laboratory. If preserved in the laboratory, however, samples must be held for at least 24 hours prior to analysis.
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Arsenic, 6.1, Poison, UN1558
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Arsenic, Total
|
|---|
| SAM 2017 Method(s) |
3050B / 3051A / 6010D / 6020B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
Analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Arsenic, 6.1, Poison, UN1558
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Arsenic, Total
|
|---|
| SAM 2017 Method(s) |
9102 (NIOSH) / 6010D / 6020B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
Analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Arsenic, 6.1, Poison, UN1558
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Arsine (analyze as total arsenic in non-air samples)
|
|---|
| SAM 2017 Method(s) |
3015A / 6010D / 6020B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
125 mL
|
|---|
| Sample Container: |
Fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
6 months with acidification. Samples must be acidified within 14 days of collection.
|
|---|
| Preservation: |
• Acidify to pH < 2 with HNO3 [If arsenic species are to be determined, remove unpreserved aliquot prior to sample preservation.]
• Acidified samples can be cooled to ≤ 6°C; keep from freezing
If sample collectors are not able to preserve samples in the field (e.g., acid preservatives are not available), the samples may be preserved in the laboratory. If preserved in the laboratory, however, samples must be held for at least 24 hours prior to analysis.
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Arsine, 2.1, Flammable gas, 2.3, Poisonous gas, UN2188
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Arsine (analyze as total arsenic in non-air samples)
|
|---|
| SAM 2017 Method(s) |
6001 (NIOSH)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
0.1 L (at 0.05 ppm) - 10 L (flow rate = 0.01 - 0.2 L/min)
|
|---|
| Sample Container: |
Solid sorbent tube (coconut shell charcoal [100 mg/50 mg])
|
|---|
| Holding Time: |
6 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of sorbent tube clean using a damp, then dry cloth. Cap tubes with plastic (not rubber) caps. Place tubes in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Arsine, 2.1, Flammable gas, 2.3, Poisonous gas, UN2188
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Arsine (analyze as total arsenic in non-air samples)
|
|---|
| SAM 2017 Method(s) |
200.7 / 200.8 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
125 mL
|
|---|
| Sample Container: |
Fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
6 months with acidification. Samples must be acidified within 14 days of collection.
|
|---|
| Preservation: |
• Acidify to pH < 2 with HNO3 [If arsenic species are to be determined, remove unpreserved aliquot prior to sample preservation.]
• Acidified samples can be cooled to ≤ 6°C; keep from freezing
If sample collectors are not able to preserve samples in the field (e.g., acid preservatives are not available), the samples may be preserved in the laboratory. If preserved in the laboratory, however, samples must be held for at least 24 hours prior to analysis.
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Arsine, 2.1, Flammable gas, 2.3, Poisonous gas, UN2188
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Arsine (analyze as total arsenic in non-air samples)
|
|---|
| SAM 2017 Method(s) |
9102 (NIOSH) / 6010D / 6020B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
Analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Arsine, 2.1, Flammable gas, 2.3, Poisonous gas, UN2188
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Arsine (analyze as total arsenic in non-air samples)
|
|---|
| SAM 2017 Method(s) |
3050B / 3051A / 6010D / 6020B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
Analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Arsine, 2.1, Flammable gas, 2.3, Poisonous gas, UN2188
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Asbestos
|
|---|
| SAM 2017 Method(s) |
10312:1995 (ISO)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
500 - 5000 L (flow rate = 1 - 10 L/min)
|
|---|
| Sample Container: |
Polycarbonate or cellulose ester filter
|
|---|
| Holding Time: |
Samples can be held indefinitely
|
|---|
| Preservation: |
None
|
|---|
| Packaging Requirements: |
Place filter in protective covering. Place protected filter in double plastic bags, and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Asbestos, 9, Class 9, NA2212
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Asbestos
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Asbestos
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Asbestos
|
|---|
| SAM 2017 Method(s) |
D5755-03 (soft surfaces-microvac) (ASTM)
[Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
200 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth, sealable glass or fluoropolymer container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
Samples can be held indefinitely
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Asbestos, 9, Class 9, NA2212
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Asbestos
|
|---|
| SAM 2017 Method(s) |
D6480-05 (ASTM)
[Tier I]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 particle-free wipe/100 cm2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth, sealable glass or fluoropolymer container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
Samples can be held indefinitely
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Asbestos, 9, Class 9, NA2212
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
BZ [Quinuclidinyl benzilate]
|
|---|
| SAM 2017 Method(s) |
TO-10A (EPA ORD)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
240 - 7200 L (flow rate = 1 - 5 L/min)
|
|---|
| Sample Container: |
Sorbent cartridge containing PUF or PUF in combination with other solid sorbent
|
|---|
| Holding Time: |
Analyze as soon as possible until holding time are available
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wrap cartridge in aluminum foil, and place in a clean sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
BZ [Quinuclidinyl benzilate]
|
|---|
| SAM 2017 Method(s) |
J. Chromatogr. B (2008) 874: 42-50
[Tier III]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Analyze as soon as possible until holding time data are available
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
BZ [Quinuclidinyl benzilate]
|
|---|
| SAM 2017 Method(s) |
3570/8290A Appendix A (EPA SW-846) / J. Chromatogr. B (2008) 874: 42-50
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Analyze as soon as possible until holding time data are available
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap containers with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
BZ [Quinuclidinyl benzilate]
|
|---|
| SAM 2017 Method(s) |
3541/3545A (EPA SW-846) / J. Chromatogr. B (2008) 874: 42-50
[Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Analyze as soon as possible until holding time data are available
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
BZ [Quinuclidinyl benzilate]
|
|---|
| SAM 2017 Method(s) |
J. Chromatogr. B (2008) 874: 42-50
[Tier III]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Analyze as soon as possible until holding time data are available
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Boron trifluoride
|
|---|
| SAM 2017 Method(s) |
ID216SG (OSHA)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
Up to 480 L (flow rate = 1 L/min)
|
|---|
| Sample Container: |
Midget glass bubbler containing 10 mL of 0.1 M NH4F; sample solution transferred to 20 mL glass vial with fluoropolymer-lined cap
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Until holding time data are available, analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Boron trifluoride, 2.3, Poisonous gas, UN1008
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Boron trifluoride
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Boron trifluoride
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Boron trifluoride
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Boron trifluoride
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Brodifacoum
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Brodifacoum
|
|---|
| SAM 2017 Method(s) |
D7644-16 (ASTM)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
• Add 10 mg of dry ascorbic acid to each 40 mL vial prior to collection
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Coumarin derivative pesticides, liquid, toxic, 6.1, Poison, UN3023
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Brodifacoum
|
|---|
| SAM 2017 Method(s) |
3541 / 3545A (EPA SW-846)/ D7644-16 (ASTM)
[Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Coumarin derivative pesticides, solid, toxic, 6.1, Poison, UN3026
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Brodifacoum
|
|---|
| SAM 2017 Method(s) |
D7644-16 (ASTM)
[Tier II]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
• Add 10 mg of dry ascorbic acid to each 40 mL vial prior to collection
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Coumarin derivative pesticides, liquid, toxic, 6.1, Poison, UN3023
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Brodifacoum
|
|---|
| SAM 2017 Method(s) |
3570 / 8290A Appendix A (EPA SW-846)/ D7644-16 (ASTM)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Coumarin derivative pesticides, solid, toxic, 6.1, Poison, UN3026
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Bromadiolone
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Bromadiolone
|
|---|
| SAM 2017 Method(s) |
3570 / 8290A Appendix A (EPA SW-846)/ D7644-16 (ASTM)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Coumarin derivative pesticides, solid, toxic, 6.1, Poison, UN3026
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Bromadiolone
|
|---|
| SAM 2017 Method(s) |
D7644-16 (ASTM)
[Tier II]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
• Add 10 mg of dry ascorbic acid to each 40 mL vial prior to collection
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Coumarin derivative pesticides, liquid, toxic, 6.1, Poison, UN3023
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Bromadiolone
|
|---|
| SAM 2017 Method(s) |
D7644-16 (ASTM)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
• Add 10 mg of dry ascorbic acid to each 40 mL vial prior to collection
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Coumarin derivative pesticides, liquid, toxic, 6.1, Poison, UN3023
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Bromadiolone
|
|---|
| SAM 2017 Method(s) |
3541 / 3545A (EPA SW-846)/ D7644-16 (ASTM)
[Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Coumarin derivative pesticides, solid, toxic, 6.1, Poison, UN3026
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Calcium arsenate (analyze as total arsenic)
|
|---|
| SAM 2017 Method(s) |
200.7 / 200.8 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
125 mL
|
|---|
| Sample Container: |
Fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
6 months with acidification. Samples must be acidified within 14 days of collection.
|
|---|
| Preservation: |
• Acidify to pH < 2 with HNO3 [If arsenic species are to be determined, remove unpreserved aliquot prior to sample preservation.]
• Acidified samples can be cooled to ≤ 6°C; keep from freezing
If sample collectors are not able to preserve samples in the field (e.g., acid preservatives are not available), the samples may be preserved in the laboratory. If preserved in the laboratory, however, samples must be held for at least 24 hours prior to analysis.
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Calcium arsenate, 6.1, Poison, UN1573
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Calcium arsenate (analyze as total arsenic)
|
|---|
| SAM 2017 Method(s) |
9102 (NIOSH) / 6010D / 6020B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or
1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
Analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Calcium arsenate, 6.1, Poison, UN1573
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Calcium arsenate (analyze as total arsenic)
|
|---|
| SAM 2017 Method(s) |
IO-3.1 / IO-3.4 / IO-3.5 (EPA ORD)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
Up to 1700 m3
|
|---|
| Sample Container: |
Filter (quartz, silica, or cellulose fiber)
|
|---|
| Holding Time: |
6 months
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Place filter in protective covering. Place protected filter in double plastic bags, and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Calcium arsenate, 6.1, Poison, UN1573
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Calcium arsenate (analyze as total arsenic)
|
|---|
| SAM 2017 Method(s) |
3050B / 3051A / 6010D / 6020B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
Analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Calcium arsenate, 6.1, Poison, UN1573
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Calcium arsenate (analyze as total arsenic)
|
|---|
| SAM 2017 Method(s) |
3015A / 6010D / 6020B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
125 mL
|
|---|
| Sample Container: |
Fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
6 months with acidification. Samples must be acidified within 14 days of collection.
|
|---|
| Preservation: |
• Acidify to pH < 2 with HNO3 [If arsenic species are to be determined, remove unpreserved aliquot prior to sample preservation.]
• Acidified samples can be cooled to ≤ 6°C; keep from freezing
If sample collectors are not able to preserve samples in the field (e.g., acid preservatives are not available), the samples may be preserved in the laboratory. If preserved in the laboratory, however, samples must be held for at least 24 hours prior to analysis.
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Calcium arsenate, 6.1, Poison, UN1573
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Carbofuran (Furadan)
|
|---|
| SAM 2017 Method(s) |
8318A (EPA SW-846)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Carbamate pesticides, solid, toxic, 6.1, UN2757
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Carbofuran (Furadan)
|
|---|
| SAM 2017 Method(s) |
3570 / 8290A Appendix A / 8318A (EPA SW-846)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Carbamate pesticides, solid, toxic, 6.1, UN2757
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Carbofuran (Furadan)
|
|---|
| SAM 2017 Method(s) |
5601 (NIOSH)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
240 - 480 L (flow rate = 0.1 - 1 L/min)
|
|---|
| Sample Container: |
Filter/solid sorbent tube (OVS-2 tube: 13 mm quartz fiber filter, XAD-2 [270 mg/140 mg])
|
|---|
| Holding Time: |
30 days if frozen; 7 days at room temperature (24°C)
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of sorbent tube clean using a damp, then dry cloth. Cap both ends of the tube with plastic caps. Place tube in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Carbamate pesticides, solid, toxic, 6.1, UN2757
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Carbofuran (Furadan)
|
|---|
| SAM 2017 Method(s) |
D7645-16 (ASTM)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
• Acidify to pH ≤ 3.8 with glacial acetic acid
• Cool to ≤ 6°C; keep from freezing
• Prior to collection of treated water samples, add 10 mg ascorbic acid to sample container
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Carbamate pesticides, liquid, toxic, 6.1, Poison, UN2992
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Carbofuran (Furadan)
|
|---|
| SAM 2017 Method(s) |
531.2 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
28 days
|
|---|
| Preservation: |
• Prior to collection, add 0.4 g potassium dihydrogen citrate and 3.2 - 4.8 mg sodium thiosulfate to sample container
• Agitate for 1 minute after collection
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Carbamate pesticides, liquid, toxic, 6.1, Poison, UN2992
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Carbon disulfide
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Carbon disulfide
|
|---|
| SAM 2017 Method(s) |
TO-15 (EPA ORD)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
1-L or 6-L canister (depending on suspected concentration)
[Method TO-15 applies to ambient concentrations of VOCs above 0.5 ppbv and typically requires VOC enrichment by concentrating up to 1 L of sample volume; however, when using current technologies, quantifications of approximately 100 pptv have been achieved with 0.5-L sample volumes.]
|
|---|
| Sample Container: |
Specially prepared stainless steel canister
For subatmospheric pressure sampling, the canister is evacuated to 0.05 mm Hg; for pressurized sampling, the sample is collected using a pump and flow control arrangement to achieve a typical 101 - 202 kPa (15 - 30 psig)
|
|---|
| Holding Time: |
30 days
|
|---|
| Preservation: |
None
|
|---|
| Packaging Requirements: |
Ship canister in container provided by laboratory
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Carbon disulfide, 3, Flammable liquid, 6.1, Poison, UN1131
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Carbon disulfide
|
|---|
| SAM 2017 Method(s) |
5035A / 8260D (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
5-g coring device or amber VOA vial
AND 1 - 2 oz. glass jar (if needed to determine percent moisture)
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Coring device (If coring device is to be cleaned and reused, samples can be transferred to an amber VOA vial.)
AND glass jar (if needed to determine percent moisture)
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days if frozen; 48 hours if not frozen
|
|---|
| Preservation: |
Cool to ≤ 6°C; freeze within 48 hours to ≤ negative (-) 7°C [Coring tools should not be frozen below -20°C.]
|
|---|
| Packaging Requirements: |
Wipe outside of coring device or container clean using a damp, then dry cloth. Place the coring device or container in a zipper bag.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Carbon disulfide, 3, Flammable liquid, 6.1, Poison, UN1131
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Carbon disulfide
|
|---|
| SAM 2017 Method(s) |
5030C / 8260D (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Screw cap VOA vial with fluoropolymer-lined septum, filled with no headspace
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days with acidification; 7 days if not acidified
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Adjust to pH < 2 with 1:1 HCl
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Carbon disulfide, 3, Flammable liquid, 6.1, Poison, UN1131
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Carbon disulfide
|
|---|
| SAM 2017 Method(s) |
524.2 / 524.3 / 524.4 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw cap VOA vial with fluoropolymer-lined septum, filled with no headspace
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days with acidification; 24 hours if not acidified
|
|---|
| Preservation: |
Prior to collection of treated water samples, add 25 mg ascorbic acid to container for removal of residual chlorine
Method 524.2:
• Adjust to pH < 2 with 1:1 HCl
Methods 524.3 and 524.4:
• Adjust to pH < 2 with maleic acid
For all samples:
• If residual chlorine is > 5 mg/L, add an additional 25 mg ascorbic acid per each 5 mg/L chlorine
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Carbon disulfide, 3, Flammable liquid, 6.1, Poison, UN1131
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Carfentanil
|
|---|
| SAM 2017 Method(s) |
3570 / 8290A Appendix A (EPA SW-846)/ J. Chromatogr. B (2014) 962: 52-58
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organic, n.o.s., 6.1, toxic, UN2810
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Carfentanil
|
|---|
| SAM 2017 Method(s) |
3520C / 3535A (EPA SW-846) / J. Chromatogr. B (2014) 962: 52-58
[Tier III]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organic, n.o.s., 6.1, toxic, UN2810
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Carfentanil
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Carfentanil
|
|---|
| SAM 2017 Method(s) |
3520C / 3535A (EPA SW-846) / J. Chromatogr. B (2014) 962: 52-58
[Tier III]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organic, n.o.s., 6.1, toxic, UN2810
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Carfentanil
|
|---|
| SAM 2017 Method(s) |
3541 / 3545A (EPA SW-846) / J. Chromatogr. B (2014) 962: 52-58
[Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organic, n.o.s., 6.1, toxic, UN2810
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Chlorfenvinphos
|
|---|
| SAM 2017 Method(s) |
3520C / 3535A / 8270E (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Chlorfenvinphos
|
|---|
| SAM 2017 Method(s) |
TO-10A (EPA ORD)
[Tier II]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
240 - 7200 L (flow rate = 1 - 5 L/min)
|
|---|
| Sample Container: |
Sorbent cartridge containing PUF or PUF in combination with other solid sorbent
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Remove PUF cartridge from sampler, wrap with aluminum foil used to store cartridge, and place in a sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Chlorfenvinphos
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Chlorfenvinphos
|
|---|
| SAM 2017 Method(s) |
3520C / 3535A / 8270E (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Chlorfenvinphos
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Chlorine
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Chlorine
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Chlorine
|
|---|
| SAM 2017 Method(s) |
4500-CI G (SM)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
500 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
Until holding time data are available, analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
Avoid excessive agitation
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Chlorine, 2.3, 5.1, Oxidizer, 8, Poison gas, UN1017
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Chlorine
|
|---|
| SAM 2017 Method(s) |
4500-CI G (SM)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
500 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
Until holding time data are available, analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
Avoid excessive agitation
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Chlorine, 2.3, 5.1, Oxidizer, 8, Poison gas, UN1017
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Chlorine
|
|---|
| SAM 2017 Method(s) |
Analyst (1999) 124(12): 1853-1857/ 4500-CI G (SM)
[Tier II]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
8 L (at 0.1 ppm) - 360 L (flow rate = 0.039 - 2.94 L/min)
|
|---|
| Sample Container: |
Prefilter and filter (fluoropolymer, 0.5 µm and silver membrane, 25 mm, 0.45 µm)
|
|---|
| Holding Time: |
30 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Place filter in protective covering. Place protected filter in double plastic bags, and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Chlorine, 2.3, 5.1, Oxidizer, 8, Poison gas, UN1017
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Chloropicrin
|
|---|
| SAM 2017 Method(s) |
551.1 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
60 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
• Prior to collection of treated water samples, add 6 mg NH4Cl to sample container
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Chloropicrin, 6.1, Poison, UN1580
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Chloropicrin
|
|---|
| SAM 2017 Method(s) |
PV2103 (OSHA)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
5 L (flow rate = 0.2 L/min)
|
|---|
| Sample Container: |
Solid sorbent tube (XAD-4 [100 mg/50 mg])
|
|---|
| Holding Time: |
Until holding time data are available, analyze immediately/ as soon as possible
|
|---|
| Preservation: |
• Cool to ≤ 6°C
• Protect from light
|
|---|
| Packaging Requirements: |
Wipe outside of sorbent tube clean using a damp, then dry cloth. Cap tubes with plastic (not rubber) caps. Place tubes in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Chloropicrin, 6.1, Poison, UN1580
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Chloropicrin
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Chloropicrin, 6.1, Poison, UN1580
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Chloropicrin
|
|---|
| SAM 2017 Method(s) |
551.1 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
60 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
• Prior to collection of treated water samples, add 6 mg NH4Cl to sample container
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Chloropicrin, 6.1, Poison, UN1580
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Chloropicrin
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Chloropicrin, 6.1, Poison, UN1580
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Chlorosarin
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/115 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Cool to ≤ 6°C; keep from freezing
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Chlorosarin
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/115 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap containers with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Chlorosarin
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/115 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap containers with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Chlorosarin
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/115 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Cool to ≤ 6°C; keep from freezing
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Chlorosarin
|
|---|
| SAM 2017 Method(s) |
TO-17 (EPA ORD)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
1 - 4 L (flow rate = 16 - 67 mL/min)
|
|---|
| Sample Container: |
Stainless steel, 3.5-inch long tubes with a 6-cm sorbent bed and 1/4-inch o.d.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wrap tube in aluminum foil, and place in a clean sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Chlorosoman
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/115 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap containers with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Chlorosoman
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/115 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap containers with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Chlorosoman
|
|---|
| SAM 2017 Method(s) |
TO-17 (EPA ORD)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
1 - 4 L (flow rate = 16 - 67 mL/min)
|
|---|
| Sample Container: |
Stainless steel, 3.5-inch long tubes with a 6-cm sorbent bed and 1/4-inch o.d.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wrap tube in aluminum foil, and place in a clean sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Chlorosoman
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/115 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Chlorosoman
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/115 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Chlorpyrifos
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Chlorpyrifos
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Chlorpyrifos
|
|---|
| SAM 2017 Method(s) |
TO-10A (EPA ORD)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
240 - 7200 L (flow rate = 1 - 5 L/min)
|
|---|
| Sample Container: |
Sorbent cartridge containing PUF or PUF in combination with other solid sorbent
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Remove PUF cartridge from sampler, wrap with aluminum foil used to store cartridge, and place in a sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Chlorpyrifos
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
For treated water samples:
Preservatives/dechlorinating agents not required, but the analyte is not affected by the following, if added to address other analytes:
• 1.6 - 2.0 mg NH4Cl
For all other samples:
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Chlorpyrifos
|
|---|
| SAM 2017 Method(s) |
525.3 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Method 525.2:
• Add sodium sulfite to empty sample container to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Acidify to pH < 2 with 1:1 HCl
• Cool to ≤ 6°C; keep from freezing
Method 525.3 (to empty sample container):
• Add 4 mg ascorbic acid to remove residual chlorine from treated water samples
• Add 14 mg trisodium EDTA, and 400 mg potassium dihydrogen citrate
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Chlorpyrifos oxon
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Chlorpyrifos oxon
|
|---|
| SAM 2017 Method(s) |
540 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
250 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Prior to collection, add solid ascorbic acid (dechlorinating agent), Trizma© base (buffering agent) and chloroacetamide (antimicrobial preservative) at concentrations of 7.75 g/L, 2 g/L and 100 mg/L, respectively to an empty sample container
• After collecting the sample, cap the container and agitate until preservative is dissolved
• Cool samples to ≤10°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Chlorpyrifos oxon
|
|---|
| SAM 2017 Method(s) |
540 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
250 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Prior to collection, add solid ascorbic acid (dechlorinating agent), Trizma© base (buffering agent) and chloroacetamide (antimicrobial preservative) at concentrations of 7.75 g/L, 2 g/L and 100 mg/L, respectively to an empty sample container
• After collecting the sample, cap the container and agitate until preservative is dissolved
• Cool samples to ≤10°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Chlorpyrifos oxon
|
|---|
| SAM 2017 Method(s) |
TO-10A (EPA ORD)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
240 - 7200 L (flow rate = 1 - 5 L/min)
|
|---|
| Sample Container: |
Sorbent cartridge containing PUF or PUF in combination with other solid sorbent
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Remove PUF cartridge from sampler, wrap with aluminum foil used to store cartridge, and place in a sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Chlorpyrifos oxon
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Crimidine
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
For treated water samples:
Preservatives/dechlorinating agents not required, but the analyte is not affected by the following, if added to address other analytes:
• 2.0 mg NH4Cl
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Pesticide, n.o.s., liquid, 6.1, Poison, UN2902
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Crimidine
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
For treated water samples:
Preservatives/dechlorinating agents not required, but the analyte is not affected by the following, if added to address other analytes:
• 2.0 mg NH4Cl
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Pesticide, n.o.s., liquid, 6.1, Poison, UN2902
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Crimidine
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or
1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Pesticide, n.o.s., solid, 6.1, Poison, UN2588
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Crimidine
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Pesticide, n.o.s., solid, 6.1, Poison, UN2588
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Crimidine
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Cyanide, Amenable to chlorination
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Cyanide, Amenable to chlorination
|
|---|
| SAM 2017 Method(s) |
3135.2l (EPA Regional Lab)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Glass or polyethylene container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
For treated water samples:
• Add 0.6 g of ascorbic acid for each liter of sample volume
For all samples:
• Adjust to pH ≥ 12 with NaOH
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Cyanide solutions n.o.s, 6.1, Poison, UN1935
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Cyanide, Amenable to chlorination
|
|---|
| SAM 2017 Method(s) |
3135.2I (EPA Regional Lab)
[Tier I]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth glass or polyethylene container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Cyanide inorganic solid n.o.s, 6.1, Poison, UN1588
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Cyanide, Amenable to chlorination
|
|---|
| SAM 2017 Method(s) |
3135.2l (EPA Regional Lab)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Glass or polyethylene container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
For treated water samples:
• Add 0.6 g of ascorbic acid for each liter of sample volume
For all samples:
• Adjust to pH ≥ 12 with NaOH
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Cyanide solutions n.o.s, 6.1, Poison, UN1935
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Cyanide, Amenable to chlorination
|
|---|
| SAM 2017 Method(s) |
3135.2I (EPA Regional Lab)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth glass or polyethylene container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Cyanide inorganic solid n.o.s, 6.1, Poison, UN1588
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Cyanide, Total
|
|---|
| SAM 2017 Method(s) |
335.4 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
125 mL
|
|---|
| Sample Container: |
Amber glass or polyethylene container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
• Add 0.6 g of ascorbic acid for each liter of sample volume
• Adjust to pH ≥ 12 with NaOH
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Cyanide solutions n.o.s, 6.1, Poison, UN1935
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Cyanide, Total
|
|---|
| SAM 2017 Method(s) |
ISM 02.3 CN (EPA CLP)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth amber glass or polyethylene container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Cyanides, inorganic, solid, n.o.s, 6.1, Poison, UN1588
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Cyanide, Total
|
|---|
| SAM 2017 Method(s) |
ISM 02.3 CN (EPA CLP)
[Tier I]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass or polyethylene container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Cyanides, inorganic, solid, n.o.s, 6.1, Poison, UN1588
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Cyanide, Total
|
|---|
| SAM 2017 Method(s) |
ISM 02.3 CN (EPA CLP)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
500 mL
|
|---|
| Sample Container: |
Amber glass or polyethylene container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
For treated water samples:
• Add 0.6 g of ascorbic acid for each liter of sample volume
For all samples:
• Adjust to pH ≥ 12 with NaOH
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Cyanide solutions n.o.s, 6.1, Poison, UN1935
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Cyanide, Total
|
|---|
| SAM 2017 Method(s) |
6010 (NIOSH)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
2 (at 5 ppm) - 90 L (flow rate = 0.05 - 0.2 L/min)
|
|---|
| Sample Container: |
Solid sorbent tube (soda lime [600 mg/200 mg])
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of sorbent tube clean using a damp, then dry cloth. Cap tubes with plastic (not rubber) caps. Place tubes in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Cyanides, inorganic, solid, n.o.s, 6.1, Poison, UN1588
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Cyanogen chloride
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Cyanogen chloride
|
|---|
| SAM 2017 Method(s) |
Encyclopedia of Anal. Chem. (2006) DOI: 10.1002/9780470027 318.a0809
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
5-g coring device or amber VOA vial
AND 1 - 2 oz. glass jar (if needed to determine percent moisture)
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Coring device (If coring device is to be cleaned and reused, samples can be transferred to an amber VOA vial.)
AND glass jar (if needed to determine percent moisture)
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days if frozen; 48 hours if not frozen
|
|---|
| Preservation: |
Cool to ≤ 6°C; freeze within 48 hours to ≤ negative (-) 7°C [Coring tools should not be frozen below -20°C.]
|
|---|
| Packaging Requirements: |
Wipe outside of coring device or container clean using a damp, then dry cloth. Place the coring device or container in a zipper bag.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Cyanogen chloride, 2.3, Poisonous gas, UN1589
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Cyanogen chloride
|
|---|
| SAM 2017 Method(s) |
Encyclopedia of Anal. Chem. (2006) DOI: 10.1002/9780470027 318.a0809
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw cap VOA vial with fluoropolymer-lined septum, filled with no headspace
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Adjust to pH < 2 with 1:1 HCl
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container lean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Cyanogen chloride, 2.3, Poisonous gas, UN1589
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Cyanogen chloride
|
|---|
| SAM 2017 Method(s) |
TO-15 (EPA ORD)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
1-L or 6-L canister (depending on suspected concentration)
[Method TO-15 applies to ambient concentrations of VOCs above 0.5 ppbv and typically requires VOC enrichment by concentrating up to 1 L of sample volume; however, when using current technologies, quantifications of approximately 100 pptv have been achieved with 0.5-L sample volumes.]
|
|---|
| Sample Container: |
Specially prepared stainless steel canister
For subatmospheric pressure sampling, the canister is evacuated to 0.05 mm Hg; for pressurized sampling, the sample is collected using a pump and flow control arrangement to achieve a typical 101 - 202 kPa (15 - 30 psig)
|
|---|
| Holding Time: |
Analyze immediately/ as soon as possible
|
|---|
| Preservation: |
None
|
|---|
| Packaging Requirements: |
Ship canister in container provided by laboratory
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Cyanogen chloride, 2.3, Poisonous gas, UN1589
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Cyanogen chloride
|
|---|
| SAM 2017 Method(s) |
Encyclopedia of Anal. Chem. (2006) DOI: 10.1002/9780470027 318.a0809
[Tier II]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw cap VOA vial with fluoropolymer-lined septum, filled with no headspace
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Adjust to pH < 2 with 1:1 HCl
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container lean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Cyanogen chloride, 2.3, Poisonous gas, UN1589
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Cyclohexyl sarin (GF)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/115 (EPA NHSRC)
[Tier I]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap containers with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Cyclohexyl sarin (GF)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/115 (EPA NHSRC)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap containers with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Cyclohexyl sarin (GF)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/115 (EPA NHSRC)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap containers with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Cyclohexyl sarin (GF)
|
|---|
| SAM 2017 Method(s) |
TO-17 (EPA ORD)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
1 - 4 L (flow rate = 16 - 67 mL/min)
|
|---|
| Sample Container: |
Stainless steel, 3.5-inch long tubes with a 6-cm sorbent bed and 1/4-inch O.D.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wrap tube in aluminum foil, and place in a clean sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Cyclohexyl sarin (GF)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/115 (EPA NHSRC)
[Tier I]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap containers with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Dichlorvos
|
|---|
| SAM 2017 Method(s) |
525.3 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Method 525.2:
• Add sodium sulfite to empty sample container to remove residual chlorine from treated water samples [Sodium sulfite can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: for a 1-L sample, add 40 - 50 mg sodium sulfite (1.6 - 2 mg/40-mL sample).]
• Acidify to pH < 2 with 1:1 HCl
• Cool to ≤ 6°C; keep from freezing
Method 525.3 (to empty sample container):
• Add 4 mg ascorbic acid to remove residual chlorine from treated water samples
• Add 14 mg trisodium EDTA, and 400 mg potassium dihydrogen citrate
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Dichlorvos
|
|---|
| SAM 2017 Method(s) |
TO-10A (EPA ORD)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
240 - 7200 L (flow rate = 1 - 5 L/min)
|
|---|
| Sample Container: |
Sorbent cartridge containing PUF or PUF in combination with other solid sorbent
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Remove PUF cartridge from sampler, wrap with aluminum foil used to store cartridge, and place in a sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Dichlorvos
|
|---|
| SAM 2017 Method(s) |
3535A / 8270E (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Dichlorvos
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Dichlorvos
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Dicrotophos
|
|---|
| SAM 2017 Method(s) |
TO-10A (EPA ORD)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
240 - 7200 L (flow rate = 1 - 5 L/min)
|
|---|
| Sample Container: |
Sorbent cartridge containing PUF or PUF in combination with other solid sorbent
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Remove PUF cartridge from sampler, wrap with aluminum foil used to store cartridge, and place in a sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Dicrotophos
|
|---|
| SAM 2017 Method(s) |
3535A / 8270E (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Dicrotophos
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Dicrotophos
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Dicrotophos
|
|---|
| SAM 2017 Method(s) |
3535A / 8270E (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Diesel Range Organics
|
|---|
| SAM 2017 Method(s) |
3520C / 3535A / 8015D (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Diesel fuel, 3, flammable, UN1203
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Diesel Range Organics
|
|---|
| SAM 2017 Method(s) |
3520C / 3535A / 8015D (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Diesel fuel, 3, flammable, UN1203
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Diesel Range Organics
|
|---|
| SAM 2017 Method(s) |
3541 / 3545A / 8015D (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Diesel fuel, 3, flammable, UN1203
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Diesel Range Organics
|
|---|
| SAM 2017 Method(s) |
3570 / 8290A Appendix A / 8015D (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Diesel fuel, 3, flammable, UN1203
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Diesel Range Organics
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Diisopropyl methyl-phosphonate (DIMP) (degradation product of GB)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-13/224 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Diisopropyl methyl-phosphonate (DIMP) (degradation product of GB)
|
|---|
| SAM 2017 Method(s) |
TO-10A (EPA ORD)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
240 - 7200 L (flow rate = 1 - 5 L/min)
|
|---|
| Sample Container: |
Sorbent cartridge containing PUF or PUF in combination with other solid sorbent
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Remove PUF cartridge from sampler, wrap with aluminum foil used to store cartridge, and place in a sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Diisopropyl methyl-phosphonate (DIMP) (degradation product of GB)
|
|---|
| SAM 2017 Method(s) |
538 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
• Prior to sample collection, add 400 µL of ammonium acetate concentrated stock and 80 µL of concentrated sodium omadine stock to sample container. [If volumes other than 40-mL are collected, the concentration of ammonium acetate and sodium omadine in the sample should be 1.5 g/L and 64 mg/L, respectively.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Diisopropyl methyl-phosphonate (DIMP) (degradation product of GB)
|
|---|
| SAM 2017 Method(s) |
D7597-16 (ASTM)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
24 hours
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Diisopropyl methyl-phosphonate (DIMP) (degradation product of GB)
|
|---|
| SAM 2017 Method(s) |
E2866-12 (ASTM)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Dimethylphosphite
|
|---|
| SAM 2017 Method(s) |
TO-10A (EPA ORD)
[Tier II]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
240 - 7200 L (flow rate = 1 - 5 L/min)
|
|---|
| Sample Container: |
Sorbent cartridge containing PUF or PUF in combination with other solid sorbent
|
|---|
| Holding Time: |
Analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Remove PUF cartridge from sampler, wrap with aluminum foil used to store cartridge, and place in a sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus compound, toxic, solid, n.o.s, 6.1, Poison, UN3464
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Dimethylphosphite
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus compound, toxic, solid, n.o.s, 6.1, Poison, UN3464
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Dimethylphosphite
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Dimethylphosphite
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus compound, toxic, solid, n.o.s, 6.1, Poison, UN3464
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Dimethylphosphite
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Dimethylphosphoramidic acid (degradation product of GA)
|
|---|
| SAM 2017 Method(s) |
D7597-16 (ASTM)
[Tier III]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
24 hours
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus compound, toxic, liquid, n.o.s, 6.1, Poison, UN3278
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Dimethylphosphoramidic acid (degradation product of GA)
|
|---|
| SAM 2017 Method(s) |
TO-10A (EPA ORD)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
240 - 7200 L (flow rate = 1 - 5 L/min)
|
|---|
| Sample Container: |
Sorbent cartridge containing PUF or PUF in combination with other solid sorbent
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Remove PUF cartridge from sampler, wrap with aluminum foil used to store cartridge, and place in a sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus compound, toxic, solid, n.o.s, 6.1, Poison, UN3464
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Dimethylphosphoramidic acid (degradation product of GA)
|
|---|
| SAM 2017 Method(s) |
E2866-12 (ASTM)
[Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus compound, toxic, solid, n.o.s, 6.1, Poison, UN3464
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Dimethylphosphoramidic acid (degradation product of GA)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-13/224 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus compound, toxic, solid, n.o.s, 6.1, Poison, UN3464
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Dimethylphosphoramidic acid (degradation product of GA)
|
|---|
| SAM 2017 Method(s) |
D7597-16 (ASTM)
[Tier III]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
24 hours
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus compound, toxic, liquid, n.o.s, 6.1, Poison, UN3278
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Diphacinone
|
|---|
| SAM 2017 Method(s) |
3541 / 3545A (EPA SW-846) / D7644-16 (ASTM)
[Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Coumarin derivative pesticides, solid, toxic, 6.1, Poison, UN3026
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Diphacinone
|
|---|
| SAM 2017 Method(s) |
D7644-16 (ASTM)
[Tier II]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
• Prior to collection of treated water samples, add 10 mg of dry ascorbic acid to sample container for removal of residual chlorine
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film. Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Coumarin derivative pesticides, liquid, toxic, 6.1, Poison, UN3023
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Diphacinone
|
|---|
| SAM 2017 Method(s) |
D7644-16 (ASTM)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
• Prior to collection of treated water samples, add 10 mg of dry ascorbic acid to sample container for removal of residual chlorine
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film. Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Coumarin derivative pesticides, liquid, toxic, 6.1, Poison, UN3023
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Diphacinone
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Diphacinone
|
|---|
| SAM 2017 Method(s) |
3570 / 8290A Appendix A (EPA SW-846) / D7644-16 (ASTM)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Coumarin derivative pesticides, solid, toxic, 6.1, Poison, UN3026
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Disulfoton
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Disulfoton
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Disulfoton
|
|---|
| SAM 2017 Method(s) |
525.3 (EPA OW)
[Tier II]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Method 525.2:
• Add sodium sulfite to empty sample container to remove residual chlorine from treated water samples [An amount equivalent to the following is recommended: for a 1-L sample, add 40 - 50 mg sodium sulfite (1.6 - 2 mg/40-mL sample).]
• Acidify to pH < 2 with 1:1 HCl
• Cool to ≤ 6°C; keep from freezing
Method 525.3 (to empty sample container):
• Add 4 mg ascorbic acid to remove residual chlorine from treated water samples
• Add 14 mg trisodium EDTA, and 400 mg potassium dihydrogen citrate
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Disulfoton
|
|---|
| SAM 2017 Method(s) |
5600 (NIOSH)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
12 - 240 L (flow rate = 0.2 to 1 L/min)
|
|---|
| Sample Container: |
Filter/solid sorbent tube (OVS-2 tube: 13 mm quartz filter, XAD-2, [270 mg/140 mg])
|
|---|
| Holding Time: |
30 days if frozen; 10 days if not frozen
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of sorbent tube clean using a damp, then dry cloth. Cap both ends of the tube with plastic caps. Place tube in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Disulfoton
|
|---|
| SAM 2017 Method(s) |
525.3 (EPA OW)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Method 525.2:
• Add sodium sulfite to empty sample container to remove residual chlorine from treated water samples [ An amount equivalent to the following is recommended: for a 1-L sample, add 40 - 50 mg sodium sulfite (1.6 - 2 mg/40-mL sample).]
• Acidify to pH < 2 with 1:1 HCl
• Cool to ≤ 6°C; keep from freezing
Method 525.3 (to empty sample container):
• Add 4 mg ascorbic acid to remove residual chlorine from treated water samples
• Add 14 mg trisodium EDTA, and 400 mg potassium dihydrogen citrate
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Disulfoton sulfone oxon
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Disulfoton sulfone oxon
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Disulfoton sulfone oxon
|
|---|
| SAM 2017 Method(s) |
525.3 (EPA OW)
[Tier III]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Method 525.2:
• Add sodium sulfite to empty sample container to remove residual chlorine from treated water samples [Sodium sulfite can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: for a 1-L sample, add 40 - 50 mg sodium sulfite (1.6 - 2 mg/40-mL sample).]
• Acidify to pH < 2 with 1:1 HCl
• Cool to ≤ 6°C; keep from freezing
Method 525.3 (to empty sample container):
• Add 4 mg ascorbic acid to remove residual chlorine from treated water samples
• Add 14 mg trisodium EDTA, and 400 mg potassium dihydrogen citrate
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Disulfoton sulfone oxon
|
|---|
| SAM 2017 Method(s) |
525.3 (EPA OW)
[Tier III]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Method 525.2:
• Add sodium sulfite to empty sample container to remove residual chlorine from treated water samples [Sodium sulfite can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: for a 1-L sample, add 40 - 50 mg sodium sulfite (1.6 - 2 mg/40-mL sample).]
• Acidify to pH < 2 with 1:1 HCl
• Cool to ≤ 6°C; keep from freezing
Method 525.3 (to empty sample container):
• Add 4 mg ascorbic acid to remove residual chlorine from treated water samples
• Add 14 mg trisodium EDTA, and 400 mg potassium dihydrogen citrate
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Disulfoton sulfone oxon
|
|---|
| SAM 2017 Method(s) |
5600 (NIOSH)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
12 - 240 L (flow rate = 0.2 to 1 L/min)
|
|---|
| Sample Container: |
Filter/solid sorbent tube (OVS-2 tube: 13 mm quartz filter, XAD-2, [270 mg/140 mg])
|
|---|
| Holding Time: |
30 days if frozen; 10 days if not frozen
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of sorbent tube clean using a damp, then dry cloth. Cap both ends of the tube with plastic caps. Place tube in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Disulfoton sulfoxide
|
|---|
| SAM 2017 Method(s) |
525.3 (EPA OW)
[Tier II]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Method 525.2:
• Add sodium sulfite to empty sample container to remove residual chlorine from treated water samples [Sodium sulfite can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: for a 1-L sample, add 40 - 50 mg sodium sulfite (1.6 - 2 mg/40-mL sample).]
• Acidify to pH < 2 with 1:1 HCl
• Cool to ≤ 6°C; keep from freezing
Method 525.3 (to empty sample container):
• Add 4 mg ascorbic acid to remove residual chlorine from treated water samples
• Add 14 mg trisodium EDTA, and 400 mg potassium dihydrogen citrate
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Disulfoton sulfoxide
|
|---|
| SAM 2017 Method(s) |
5600 (NIOSH)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
12 - 240 L (flow rate = 0.2 to 1 L/min)
|
|---|
| Sample Container: |
Filter/solid sorbent tube (OVS-2 tube: 13 mm quartz filter, XAD-2, [270 mg/140 mg])
|
|---|
| Holding Time: |
30 days if frozen;
10 days if not frozen
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of sorbent tube clean using a damp, then dry cloth. Cap both ends of the tube with plastic caps. Place tube in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Disulfoton sulfoxide
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Disulfoton sulfoxide
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Disulfoton sulfoxide
|
|---|
| SAM 2017 Method(s) |
525.3 (EPA OW)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Method 525.2:
• Add sodium sulfite to empty sample container to remove residual chlorine from treated water samples [Sodium sulfite can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: for a 1-L sample, add 40 - 50 mg sodium sulfite (1.6 - 2 mg/40-mL sample).]
• Acidify to pH < 2 with 1:1 HCl
• Cool to ≤ 6°C; keep from freezing
Method 525.3 (to empty sample container):
• Add 4 mg ascorbic acid to remove residual chlorine from treated water samples
• Add 14 mg trisodium EDTA, and 400 mg potassium dihydrogen citrate
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Disulfoton sulfoxide oxon
|
|---|
| SAM 2017 Method(s) |
525.3 (EPA OW)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Method 525.2:
• Add sodium sulfite to empty sample container to remove residual chlorine from treated water samples [Sodium sulfite can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: for a 1-L sample, add 40 - 50 mg sodium sulfite (1.6 - 2 mg/40-mL sample).]
• Acidify to pH < 2 with 1:1 HCl
• Cool to ≤ 6°C; keep from freezing
Method 525.3 (to empty sample container):
• Add 4 mg ascorbic acid to remove residual chlorine from treated water samples
• Add 14 mg trisodium EDTA, and 400 mg potassium dihydrogen citrate
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Disulfoton sulfoxide oxon
|
|---|
| SAM 2017 Method(s) |
5600 (NIOSH)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
12 - 240 L (flow rate = 0.2 to 1 L/min)
|
|---|
| Sample Container: |
Filter/solid sorbent tube (OVS-2 tube: 13 mm quartz filter, XAD-2, [270 mg/140 mg])
|
|---|
| Holding Time: |
30 days if frozen;
10 days if not frozen
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of sorbent tube clean using a damp, then dry cloth. Cap both ends of the tube with plastic caps. Place tube in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Disulfoton sulfoxide oxon
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Disulfoton sulfoxide oxon
|
|---|
| SAM 2017 Method(s) |
525.3 (EPA OW)
[Tier II]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Method 525.2:
• Add sodium sulfite to empty sample container to remove residual chlorine from treated water samples [Sodium sulfite can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: for a 1-L sample, add 40 - 50 mg sodium sulfite (1.6 - 2 mg/40-mL sample).]
• Acidify to pH < 2 with 1:1 HCl
• Cool to ≤ 6°C; keep from freezing
Method 525.3 (to empty sample container):
• Add 4 mg ascorbic acid to remove residual chlorine from treated water samples
• Add 14 mg trisodium EDTA, and 400 mg potassium dihydrogen citrate
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Disulfoton sulfoxide oxon
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
EA2192 [S-2-(diisopropylamino)ethyl methylphosphonothioic acid] (hydrolysis product of VX)
|
|---|
| SAM 2017 Method(s) |
TO-10A (EPA ORD)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
240 - 7200 L (flow rate = 1 - 5 L/min)
|
|---|
| Sample Container: |
Sorbent cartridge containing PUF or PUF in combination with other solid sorbent
|
|---|
| Holding Time: |
Until holding time data are available, analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap containers with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
EA2192 [S-2-(diisopropylamino)ethyl methylphosphonothioic acid] (hydrolysis product of VX)
|
|---|
| SAM 2017 Method(s) |
3570 / 8290A Appendix A (EPA SW-846) / EPA/600/R-15/097 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap containers with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
EA2192 [S-2-(diisopropylamino)ethyl methylphosphonothioic acid] (hydrolysis product of VX)
|
|---|
| SAM 2017 Method(s) |
3541 / 3545A (EPA SW-846) / EPA/600/R-15/097 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Until holding time data are available, analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap containers with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
EA2192 [S-2-(diisopropylamino)ethyl methylphosphonothioic acid] (hydrolysis product of VX)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-15/097 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap containers with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
EA2192 [S-2-(diisopropylamino)ethyl methylphosphonothioic acid] (hydrolysis product of VX)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-15/097 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap containers with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Ethyl methylphosphonic acid (EMPA) (degradation product of VX)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-13/224 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus compound, toxic, solid, n.o.s, 6.1, Poison, UN3464
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Ethyl methylphosphonic acid (EMPA) (degradation product of VX)
|
|---|
| SAM 2017 Method(s) |
D7597-16 (ASTM)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
24 hours
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus compound, toxic, liquid, n.o.s, 6.1, Poison, UN3278
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Ethyl methylphosphonic acid (EMPA) (degradation product of VX)
|
|---|
| SAM 2017 Method(s) |
E2866-12 (ASTM)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus compound, toxic, solid, n.o.s, 6.1, Poison, UN3464
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Ethyl methylphosphonic acid (EMPA) (degradation product of VX)
|
|---|
| SAM 2017 Method(s) |
TO-10A (EPA ORD)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
240 - 7200 L (flow rate = 1 - 5 L/min)
|
|---|
| Sample Container: |
Sorbent cartridge containing PUF or PUF in combination with other solid sorbent
|
|---|
| Holding Time: |
Until holding time data are available, analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Remove PUF cartridge from sampler, wrap with aluminum foil used to store cartridge, and place in a sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus compound, toxic, solid, n.o.s, 6.1, Poison, UN3464
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Ethyl methylphosphonic acid (EMPA) (degradation product of VX)
|
|---|
| SAM 2017 Method(s) |
D7597-16 (ASTM)
[Tier III]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
24 hours
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus compound, toxic, liquid, n.o.s, 6.1, Poison, UN3278
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Ethyldichloroarsine (ED)
|
|---|
| SAM 2017 Method(s) |
3535A / 8270E (EPA SW-846)
[Tier III]
.
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Until holding time data are available, analyze immediately/ as soon as possible
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Ethyldichloroarsine, 6.1, Poison, UN1892
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Ethyldichloroarsine (ED)
|
|---|
| SAM 2017 Method(s) |
9102 (NIOSH) / 8270E (EPA SW-846)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Ethyldichloroarsine, 6.1, Poison, UN1892
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Ethyldichloroarsine (ED)
|
|---|
| SAM 2017 Method(s) |
TO-15 (EPA ORD)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
1-L or 6-L canister (depending on suspected concentration)
[Method TO-15 applies to ambient concentrations of VOCs above 0.5 ppbv and typically requires VOC enrichment by concentrating up to 1 L of sample volume; however, when using current technologies, quantifications of approximately 100 pptv have been achieved with 0.5-L sample volumes.]
|
|---|
| Sample Container: |
Specially prepared stainless steel canister
For subatmospheric pressure sampling, the canister is evacuated to 0.05 mm Hg; for pressurized sampling, the sample is collected using a pump and flow control arrangement to achieve a typical 101 - 202 kPa (15 - 30 psig)
|
|---|
| Holding Time: |
Analyze immediately/ as soon as possible
|
|---|
| Preservation: |
None
|
|---|
| Packaging Requirements: |
Ship canister in container provided by laboratory
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Ethyldichloroarsine, 6.1, Poison, UN1892
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Ethyldichloroarsine (ED)
|
|---|
| SAM 2017 Method(s) |
3535A / 8270E (EPA SW-846)
[Tier III]
.
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Until holding time data are available, analyze immediately/ as soon as possible
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Ethyldichloroarsine, 6.1, Poison, UN1892
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Ethyldichloroarsine (ED)
|
|---|
| SAM 2017 Method(s) |
3541 / 3545A / 8270E (EPA SW-846)
[Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Until holding time data are available, analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Ethyldichloroarsine, 6.1, Poison, UN1892
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Ethylene oxide
|
|---|
| SAM 2017 Method(s) |
TO-15 (EPA ORD)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
1-L or 6-L canister (depending on suspected concentration)
[Method TO-15 applies to ambient concentrations of VOCs above 0.5 ppbv and typically requires VOC enrichment by concentrating up to 1 L of sample volume; however, when using current technologies, quantifications of approximately 100 pptv have been achieved with 0.5-L sample volumes.]
|
|---|
| Sample Container: |
Specially prepared stainless steel canister
For subatmospheric pressure sampling, the canister is evacuated to 0.05 mm Hg; for pressurized sampling, the sample is collected using a pump and flow control arrangement to achieve a typical 101 - 202 kPa (15 - 30 psig)
|
|---|
| Holding Time: |
30 days
|
|---|
| Preservation: |
None
|
|---|
| Packaging Requirements: |
Ship canister in container provided by laboratory
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Ethylene oxide (concentration dependent, refer to 40 CFR 172.101 for more information)
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Ethylene oxide
|
|---|
| SAM 2017 Method(s) |
5030C / 8260D (EPA SW-846)
[Tier II]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw cap VOA vial with fluoropolymer-lined septum, filled with no headspace
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days with acidification; 7 days if not acidified
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Adjust to pH < 2 with 1:1 HCl
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Ethylene oxide (concentration dependent, refer to 40 CFR 172.101 for more information)
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Ethylene oxide
|
|---|
| SAM 2017 Method(s) |
5030C / 8260D (EPA SW-846)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw cap VOA vial with fluoropolymer-lined septum, filled with no headspace
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days with acidification; 7 days if not acidified
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Adjust to pH < 2 with 1:1 HCl
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Ethylene oxide (concentration dependent, refer to 40 CFR 172.101 for more information)
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Ethylene oxide
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Ethylene oxide
|
|---|
| SAM 2017 Method(s) |
5035A / 8260D (EPA SW-846)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
5-g coring device or amber VOA vial
AND 1 - 2 oz. glass jar (if needed to determine percent moisture)
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Coring device (If coring device is to be cleaned and reused, samples can be transferred to an amber VOA vial.)
AND glass jar (if needed to determine percent moisture)
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days if frozen; 48 hours if not frozen
|
|---|
| Preservation: |
Cool to ≤ 6°C; freeze within 48 hours to ≤ negative (-) 7°C [Coring tools should not be frozen below -20°C.]
|
|---|
| Packaging Requirements: |
Wipe outside of coring device or container clean using a damp, then dry cloth. Place the coring device or container in a zipper bag.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Ethylene oxide (concentration dependent, refer to 40 CFR 172.101 for more information)
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Fenamiphos
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Analyze immediately/ as soon as possible.
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Fenamiphos
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Fenamiphos
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Fenamiphos
|
|---|
| SAM 2017 Method(s) |
525.3 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Method 525.2:
• Add sodium sulfite to empty sample container to remove residual chlorine from treated water samples [Sodium sulfite can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: for a 1-L sample, add 40 - 50 mg sodium sulfite (1.6 - 2 mg/40-mL sample).]
• Acidify to pH < 2 with 1:1 HCl
• Cool to ≤ 6°C; keep from freezing
Method 525.3 (to empty sample container):
• Add 4 mg ascorbic acid to remove residual chlorine from treated water samples
• Add 14 mg trisodium EDTA, and 400 mg potassium dihydrogen citrate
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Fenamiphos
|
|---|
| SAM 2017 Method(s) |
TO-10A (EPA ORD)
[Tier II]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
240 - 7200 L (flow rate = 1 - 5 L/min)
|
|---|
| Sample Container: |
Sorbent cartridge containing PUF or PUF in combination with other solid sorbent
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Remove PUF cartridge from sampler, wrap with aluminum foil used to store cartridge, and place in a sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Fentanyl
|
|---|
| SAM 2017 Method(s) |
3541 / 3545A (EPA SW-846) / J. Chromatogr. A (2011) 1218: 1620 - 1649
[Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Fentanyl
|
|---|
| SAM 2017 Method(s) |
3570 / 8290A Appendix A (EPA SW-846) / J. Chromatogr. A (2011) 1218: 1620 - 1649
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Fentanyl
|
|---|
| SAM 2017 Method(s) |
3520C / 3535A (EPA SW-846) /
J. Chromatogr. A (2011) 1218: 1620 - 1649
[Tier III]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Fentanyl
|
|---|
| SAM 2017 Method(s) |
3520C / 3535A (EPA SW-846) / J. Chromatogr. A (2011) 1218: 1620 - 1649
[Tier III]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Fentanyl
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Fluoride
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Fluoride
|
|---|
| SAM 2017 Method(s) |
300.1, Rev 1.0 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
28 days
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Fluoride
|
|---|
| SAM 2017 Method(s) |
300.1, Rev 1.0 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
28 days
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Fluoride
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Fluoride
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Fluoroacetamide
|
|---|
| SAM 2017 Method(s) |
J. Chromatogr. B (2008) 876(1): 103-108
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
TBD
|
|---|
| Sample Container: |
TBD
|
|---|
| Holding Time: |
Until holding time data are available, analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Fluoroacetamide, 6.1, Poison, UN1687
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Fluoroacetamide
|
|---|
| SAM 2017 Method(s) |
J. Chromatogr. B (2008) 876(1): 103-108
[Tier II]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Until holding time data are available, analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Fluoroacetamide, 6.1, Poison, UN1687
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Fluoroacetamide
|
|---|
| SAM 2017 Method(s) |
J. Chromatogr. B (2008) 876(1): 103-108
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Until holding time data are available, analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Fluoroacetamide, 6.1, Poison, UN1687
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Fluoroacetamide
|
|---|
| SAM 2017 Method(s) |
J. Chromatogr. B (2008) 876(1): 103-108
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Until holding time data are available, analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Fluoroacetamide, 6.1, Poison, UN1687
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Fluoroacetamide
|
|---|
| SAM 2017 Method(s) |
J. Chromatogr. B (2008) 876(1): 103-108
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Until holding time data are available, analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Fluoroacetamide, 6.1, Poison, UN1687
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Fluoroacetic acid and fluoroacetate salts (analyze as fluoroacetate ion)
|
|---|
| SAM 2017 Method(s) |
J. Chromatogr. A (2007) 1139: 271-278
[ Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Fluoroacetic acid, 6.1, Poison, UN2642
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Fluoroacetic acid and fluoroacetate salts (analyze as fluoroacetate ion)
|
|---|
| SAM 2017 Method(s) |
J. Chromatogr. A (2007) 1139: 271-278
[Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Fluoroacetic acid, 6.1, Poison, UN2642
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Fluoroacetic acid and fluoroacetate salts (analyze as fluoroacetate ion)
|
|---|
| SAM 2017 Method(s) |
J. Chromatogr. B (2010) 878: 1045-1050
[Tier III]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Until holding time data are available, analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Fluoroacetic acid, 6.1, Poison, UN2642
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Fluoroacetic acid and fluoroacetate salts (analyze as fluoroacetate ion)
|
|---|
| SAM 2017 Method(s) |
J. Chromatogr. B (2010) 878: 1045-1050
[Tier III]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Until holding time data are available, analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Fluoroacetic acid, 6.1, Poison, UN2642
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Fluoroacetic acid and fluoroacetate salts (analyze as fluoroacetate ion)
|
|---|
| SAM 2017 Method(s) |
S301-1 (NIOSH) / J. Chromatogr. A (2007) 1139: 271-278
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
Up to 480 L (at 1.5 - 2.0 L/min)
|
|---|
| Sample Container: |
Cellulose ester membrane filter / cleaned and rinsed glass or plastic bottles
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
Until holding time data are available, analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Place filter in protective covering. Place protected filter in double plastic bags, and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Fluoroacetic acid, 6.1, Poison, UN2642
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Fluorosilicic acid (analyze as fluoride)
|
|---|
| SAM 2017 Method(s) |
300.1, Rev 1.0 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
28 days
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Fluorosilicic acid (analyze as fluoride)
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Fluorosilicic acid (analyze as fluoride)
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Fluorosilicic acid (analyze as fluoride)
|
|---|
| SAM 2017 Method(s) |
300.1, Rev 1.0 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
28 days
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Fluorosilicic acid (analyze as fluoride)
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Formaldehyde
|
|---|
| SAM 2017 Method(s) |
8315A (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
100 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
3 days
|
|---|
| Preservation: |
• Preserve to pH 5.0 with 1:1 HCl or NaOH
• Cool to ≤ 6°C; keep from freezing
• Add 10 mg NH4Cl to remove residual chlorine from treated water samples
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Formaldehyde (concentration dependent, refer to 40 CFR 172.101 for more information).
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Formaldehyde
|
|---|
| SAM 2017 Method(s) |
2016 (NIOSH)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
1 L (at 0.25 mg/m3) - 15 L (at 2.5 mg/m3)
(flow rate = 0.03 - 1.5 L/min)
|
|---|
| Sample Container: |
Dinitrophenylhydrazine (DNPH)-coated silica gel cartridge
|
|---|
| Holding Time: |
30 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Place end caps onto the cartridge and seal sampler in an envelope. Place cartridge in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Formaldehyde (concentration dependent, refer to 40 CFR 172.101 for more information)
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Formaldehyde
|
|---|
| SAM 2017 Method(s) |
556.1 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
30 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with polypropylene screw cap equipped with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Prior to collecting treated water samples, add 15 mg copper sulfate pentahydrate and 15 mg NH4Cl to sample container
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Formaldehyde (concentration dependent, refer to 40 CFR 172.101 for more information)
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Formaldehyde
|
|---|
| SAM 2017 Method(s) |
8315A (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
3 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Formaldehyde (concentration dependent, refer to 40 CFR 172.101 for more information)
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Formaldehyde
|
|---|
| SAM 2017 Method(s) |
3570 / 8290A Appendix A / 8315A (EPA SW-846)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
3 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Formaldehyde (concentration dependent, refer to 40 CFR 172.101 for more information)
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Gasoline Range Organics
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Gasoline Range Organics
|
|---|
| SAM 2017 Method(s) |
5030C / 8015D (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw cap VOA vial with fluoropolymer-lined septum, filled with no headspace
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days with acidification; 7 days if not acidified
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Adjust to pH < 2 with 1:1 HCl
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier AND Gasoline identification set, 2.3, Poison gas, NA9035 shipping label
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Gasoline Range Organics
|
|---|
| SAM 2017 Method(s) |
3570 / 8290A Appendix A / 8015D (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier AND Gasoline identification set, 2.3, Poison gas, NA9035
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Gasoline Range Organics
|
|---|
| SAM 2017 Method(s) |
5035A / 8015D (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
5-g coring device or amber VOA vial
AND 1 - 2 oz. glass jar (if needed to determine percent moisture)
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Coring device (If coring device is to be cleaned and reused, samples can be transferred to an amber VOA vial.)
AND glass jar (if needed to determine percent moisture)
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days if frozen;
48 hours if not frozen
|
|---|
| Preservation: |
Cool to ≤ 6°C; freeze within 48 hours to ≤ negative (-) 7°C [Coring tools should not be frozen below -20°C.]
|
|---|
| Packaging Requirements: |
Wipe outside of coring device or container clean using a damp, then dry cloth. Place the coring device or container in a zipper bag.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier AND Gasoline identification set, 2.3, Poison gas, NA9035
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Gasoline Range Organics
|
|---|
| SAM 2017 Method(s) |
5030C / 8015D (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw cap VOA vial with fluoropolymer-lined septum, filled with no headspace
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days with acidification; 7 days if not acidified
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Adjust to pH < 2 with 1:1 HCl
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier AND Gasoline identification set, 2.3, Poison gas, NA9035 shipping label
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX)
|
|---|
| SAM 2017 Method(s) |
8330B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND RDX, 1.1, Explosive, UN0483
Samples containing secondary explosives at concentrations less than 10% by weight (100,000 mg/kg) or primary explosives at concentrations less than 2% can be sent as normal environmental samples. Consult laboratory on specifics regarding shipping label and shipping requirements for samples with concentrations greater than these amounts.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX)
|
|---|
| SAM 2017 Method(s) |
3535A / 8330B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND RDX, 1.1, Explosive, UN0483
Samples containing secondary explosives at concentrations less than 10% by weight (100,000 mg/kg) or primary explosives at concentrations less than 2% can be sent as normal environmental samples. Consult laboratory on specifics regarding shipping label and shipping requirements for samples with concentrations greater than these amounts.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX)
|
|---|
| SAM 2017 Method(s) |
3535A / 8330B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND RDX, 1.1, Explosive, UN0483
Samples containing secondary explosives at concentrations less than 10% by weight (100,000 mg/kg) or primary explosives at concentrations less than 2% can be sent as normal environmental samples. Consult laboratory on specifics regarding shipping label and shipping requirements for samples with concentrations greater than these amounts.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX)
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX)
|
|---|
| SAM 2017 Method(s) |
3570 / 8290A Appendix A / 8330B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND RDX, 1.1, Explosive, UN0483
Samples containing secondary explosives at concentrations less than 10% by weight (100,000 mg/kg) or primary explosives at concentrations less than 2% can be sent as normal environmental samples. Consult laboratory on specifics regarding shipping label and shipping requirements for samples with concentrations greater than these amounts.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Hexamethylene triperoxidediamine (HMTD)
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Hexamethylene triperoxidediamine (HMTD)
|
|---|
| SAM 2017 Method(s) |
3535A / 8330B (EPA SW-846) / Analyst (2001) 126:1689-1693
[Tier II]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND HMTD, 1.1, Explosive
Samples containing secondary explosives at concentrations less than 10% by weight (100,000 mg/kg) or primary explosives at concentrations less than 2% can be sent as normal environmental samples. Consult laboratory on specifics regarding shipping label and shipping requirements for samples with concentrations greater than these amounts.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Hexamethylene triperoxidediamine (HMTD)
|
|---|
| SAM 2017 Method(s) |
3535A / 8330B (EPA SW-846) / Analyst (2001) 126:1689-1693
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND HMTD, 1.1, Explosive
Samples containing secondary explosives at concentrations less than 10% by weight (100,000 mg/kg) or primary explosives at concentrations less than 2% can be sent as normal environmental samples. Consult laboratory on specifics regarding shipping label and shipping requirements for samples with concentrations greater than these amounts.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Hexamethylene triperoxidediamine (HMTD)
|
|---|
| SAM 2017 Method(s) |
8330B (EPA SW-846) / Analyst (2001) 126:1689-1693
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND HMTD, 1.1, Explosive
Samples containing secondary explosives at concentrations less than 10% by weight (100,000 mg/kg) or primary explosives at concentrations less than 2% can be sent as normal environmental samples. Consult laboratory on specifics regarding shipping label and shipping requirements for samples with concentrations greater than these amounts.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Hexamethylene triperoxidediamine (HMTD)
|
|---|
| SAM 2017 Method(s) |
3570 / 8290A Appendix A (EPA SW-846) / Analyst (2001) 126:1689-1693
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND HMTD, 1.1 , Explosive
Samples containing secondary explosives at concentrations less than 10% by weight (100,000 mg/kg) or primary explosives at concentrations less than 2% can be sent as normal environmental samples. Consult laboratory on specifics regarding shipping label and shipping requirements for samples with concentrations greater than these amounts.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Hydrogen bromide
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Hydrogen bromide
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Hydrogen bromide
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Hydrogen bromide
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Hydrogen bromide
|
|---|
| SAM 2017 Method(s) |
7907 (NIOSH)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
30 - 600 L (flow rate = 2 L/min)
|
|---|
| Sample Container: |
Two filters in series separated with chemically inert spacer:
• pre-filter: 37-mm diameter quartz fiber
• sampling filter: 37-mm diameter quartz fiber impregnated with 1 M 500-µL Na2CO3
|
|---|
| Holding Time: |
28 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of filter clean using a damp, then dry cloth. Place filter in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Hydrogen bromide, 2.3, Poisonous gas, UN1048
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Hydrogen chloride
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Hydrogen chloride
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Hydrogen chloride
|
|---|
| SAM 2017 Method(s) |
7907 (NIOSH)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
30 - 600 L (flow rate = 2 L/min)
|
|---|
| Sample Container: |
Two filters in series separated with chemically inert spacer:
• pre-filter: 37-mm diameter quartz fiber
• sampling filter: 37-mm diameter quartz fiber impregnated with 1 M 500-µL Na2CO3
|
|---|
| Holding Time: |
28 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of filter clean using a damp, then dry cloth. Place filter in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Hydrogen chloride, 2.3, Poisonous gas, UN1050
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Hydrogen chloride
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Hydrogen chloride
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Hydrogen cyanide
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Hydrogen cyanide
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Hydrogen cyanide
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Hydrogen cyanide
|
|---|
| SAM 2017 Method(s) |
6010 (NIOSH)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
2 (at 5 ppm) - 90 L (flow rate = 0.05 - 0.2 L/min)
|
|---|
| Sample Container: |
Solid sorbent tube (soda lime [600 mg/200 mg])
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of sorbent tube clean using a damp, then dry cloth. Cap tubes with plastic (not rubber) caps. Place tubes in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Hydrogen cyanide, 2.3, Poisonous gas, UN1956
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Hydrogen cyanide
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Hydrogen fluoride
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Hydrogen fluoride
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Hydrogen fluoride
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Hydrogen fluoride
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Hydrogen fluoride
|
|---|
| SAM 2017 Method(s) |
7906 (NIOSH)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
30 - 600 L (flow rate = 2 L/min)
|
|---|
| Sample Container: |
Two filters in series separated by a chemically inert spacer:
• pre-filter: cellulose nitrate, 0.8 µm pore size, 37-mm diameter
• treated filter: cellulose nitrate impregnated with 0.75 M Na2CO3, 0.8 µm pore size, 37-mm diameter
|
|---|
| Holding Time: |
28 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of filter clean using a damp, then dry cloth. Place filter in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Hydrogen fluoride, 2.3, Poisonous gas, Corrosive, UN1052
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Hydrogen sulfide
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Hydrogen sulfide
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Hydrogen sulfide
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Hydrogen sulfide
|
|---|
| SAM 2017 Method(s) |
6013 (NIOSH)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
1.2 (at 10 ppm) - 40 L (flow rate = 0.1 - 1.5 L/min; 0.2 L/min is recommended)
|
|---|
| Sample Container: |
Filter/solid sorbent tube (0.5 µm/coconut shell charcoal [400 mg/200 mg])
|
|---|
| Holding Time: |
21 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe filter and sorbent tube clean, using a damp, then dry cloth. Place filter and sorbent tube in double plastic bags, and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Hydrogen sulfide, 2.3, Poisonous gas, Corrosive, UN1053
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Hydrogen sulfide
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Isopropyl methylphosphonic acid (IMPA) (degradation product of GB)
|
|---|
| SAM 2017 Method(s) |
TO-10A (EPA ORD)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
240 - 7200 L (flow rate = 1 - 5 L/min)
|
|---|
| Sample Container: |
Sorbent cartridge containing PUF or PUF in combination with other solid sorbent
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Remove PUF cartridge from sampler, wrap with aluminum foil used to store cartridge, and place in a sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus compound, toxic, solid, n.o.s, 6.1, Poison, UN3464
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Isopropyl methylphosphonic acid (IMPA) (degradation product of GB)
|
|---|
| SAM 2017 Method(s) |
D7597-16 (ASTM)
[Tier III]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
24 hours
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus compound, toxic, liquid, n.o.s, 6.1, Poison, UN3278
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Isopropyl methylphosphonic acid (IMPA) (degradation product of GB)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-13/224 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus compound, toxic, solid, n.o.s, 6.1, Poison, UN3464
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Isopropyl methylphosphonic acid (IMPA) (degradation product of GB)
|
|---|
| SAM 2017 Method(s) |
E2866-12 (ASTM)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus compound, toxic, solid, n.o.s, 6.1, Poison, UN3464
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Isopropyl methylphosphonic acid (IMPA) (degradation product of GB)
|
|---|
| SAM 2017 Method(s) |
D7597-16 (ASTM)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
24 hours
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus compound, toxic, liquid, n.o.s, 6.1, Poison, UN3278
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Kerosene
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Kerosene
|
|---|
| SAM 2017 Method(s) |
3520C / 3535A / 8015D (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Kerosene, 3, Flammable, UN1223
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Kerosene
|
|---|
| SAM 2017 Method(s) |
3570 / 8290A Appendix A / 8015D (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Kerosene, 3, Flammable, UN1223
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Kerosene
|
|---|
| SAM 2017 Method(s) |
3541 / 3545A / 8015D (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Kerosene, 3, Flammable, UN1223
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Kerosene
|
|---|
| SAM 2017 Method(s) |
3520C / 3535A / 8015D (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Kerosene, 3, Flammable, UN1223
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Lead arsenate (analyze as total arsenic)
|
|---|
| SAM 2017 Method(s) |
3050B / 3051A / 6010D / 6020B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
Analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Lead arsenate, 6.1, Poison, UN1617
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Lead arsenate (analyze as total arsenic)
|
|---|
| SAM 2017 Method(s) |
9102 (NIOSH) / 6010D / 6020B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
Analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Lead arsenate, 6.1, Poison, UN1617
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Lead arsenate (analyze as total arsenic)
|
|---|
| SAM 2017 Method(s) |
IO-3.1 / IO-3.4 / IO-3.5 (EPA ORD)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
Up to 1700 m3
|
|---|
| Sample Container: |
Filter (quartz, silica, or cellulose fiber)
|
|---|
| Holding Time: |
6 months
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Place filter in protective covering. Place protected filter in double plastic bags, and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Lead arsenate, 6.1, Poison, UN1617
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Lead arsenate (analyze as total arsenic)
|
|---|
| SAM 2017 Method(s) |
3015A / 6010D / 6020B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
125 mL
|
|---|
| Sample Container: |
Fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
6 months with acidification. Samples must be acidified within 14 days of collection.
|
|---|
| Preservation: |
• Acidify to pH < 2 with HNO3 [If arsenic species are to be determined, remove unpreserved aliquot prior to sample preservation.]
• Acidified samples can be cooled to ≤ 6°C; keep from freezing
If sample collectors are not able to preserve samples in the field (e.g., acid preservatives are not available), the samples may be preserved in the laboratory. If preserved in the laboratory, however, samples must be held for at least 24 hours prior to analysis.
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Lead arsenate, 6.1, Poison, UN1617
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Lead arsenate (analyze as total arsenic)
|
|---|
| SAM 2017 Method(s) |
200.7 / 200.8 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
125 mL
|
|---|
| Sample Container: |
Fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
6 months with acidification. Samples must be acidified within 14 days of collection.
|
|---|
| Preservation: |
• Acidify to pH < 2 with HNO3 [If arsenic species are to be determined, remove unpreserved aliquot prior to sample preservation.]
• Acidified samples can be cooled to ≤ 6°C; keep from freezing
If sample collectors are not able to preserve samples in the field (e.g., acid preservatives are not available), the samples may be preserved in the laboratory. If preserved in the laboratory, however, samples must be held for at least 24 hours prior to analysis.
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Lead arsenate, 6.1, Poison, UN1617
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Lewisite 1 (L-1)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-15/258 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
VOA vial with fluoropolymer-lined cap
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap containers with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Lewisite 1 (L-1)
|
|---|
| SAM 2017 Method(s) |
IO-3.1 / IO-3.4/IO-3.5 (EPA ORD)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
Up to 1700 m3
|
|---|
| Sample Container: |
Filter (quartz, silica, or cellulose fiber)
|
|---|
| Holding Time: |
6 months
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Place filter in protective covering. Place protected filter in double plastic bags, and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Lewisite 1 (L-1)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-15/258 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
VOA vial with fluoropolymer-lined cap
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap containers with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Lewisite 1 (L-1)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-15/258 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
VOA vial with fluoropolymer-lined cap
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Lewisite 1 (L-1)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-15/258 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
VOA vial with fluoropolymer-lined cap
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Lewisite 2 (L-2)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-15/258 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
VOA vial with fluoropolymer-lined cap
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Lewisite 2 (L-2)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-15/258 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
VOA vial with fluoropolymer-lined cap
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap containers with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Lewisite 2 (L-2)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-15/258 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
VOA vial with fluoropolymer-lined cap
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap containers with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Lewisite 2 (L-2)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-15/258 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
VOA vial with fluoropolymer-lined cap
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Lewisite 2 (L-2)
|
|---|
| SAM 2017 Method(s) |
IO-3.1 / IO-3.4/IO-3.5 (EPA ORD)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
Up to 1700 m3
|
|---|
| Sample Container: |
Filter (quartz, silica, or cellulose fiber)
|
|---|
| Holding Time: |
6 months
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Place filter in protective covering. Place protected filter in double plastic bags, and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Lewisite 3 (L-3)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-15/258 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
VOA vial with fluoropolymer-lined cap
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Lewisite 3 (L-3)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-15/258 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
VOA vial with fluoropolymer-lined cap
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap containers with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Lewisite 3 (L-3)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-15/258 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
VOA vial with fluoropolymer-lined cap
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap containers with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Lewisite 3 (L-3)
|
|---|
| SAM 2017 Method(s) |
IO-3.1 / IO-3.4/IO-3.5 (EPA ORD)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
Up to 1700 m3
|
|---|
| Sample Container: |
Filter (quartz, silica, or cellulose fiber)
|
|---|
| Holding Time: |
6 months
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Place filter in protective covering. Place protected filter in double plastic bags, and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Lewisite 3 (L-3)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-15/258 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
VOA vial with fluoropolymer-lined cap
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Lewisite oxide (degradation product of Lewisite) (analyze as total arsenic)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-15/258 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Lewisite oxide (degradation product of Lewisite) (analyze as total arsenic)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-15/258 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Lewisite oxide (degradation product of Lewisite) (analyze as total arsenic)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-15/258 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
• Acidify to pH < 2 with HNO3
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Lewisite oxide (degradation product of Lewisite) (analyze as total arsenic)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-15/258 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
• Acidify to pH < 2 with HNO3
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Lewisite oxide (degradation product of Lewisite) (analyze as total arsenic)
|
|---|
| SAM 2017 Method(s) |
IO-3.1 / IO-3.4 / IO-3.5 (EPA ORD)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
Up to 1700 m3
|
|---|
| Sample Container: |
Filter (quartz, silica, or cellulose fiber)
|
|---|
| Holding Time: |
6 months
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Mercuric chloride (analyze as total mercury)
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Mercuric chloride (analyze as total mercury)
|
|---|
| SAM 2017 Method(s) |
245.1 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
125 mL
|
|---|
| Sample Container: |
Fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
28 days
|
|---|
| Preservation: |
Acidify to pH < 2 with HNO3
If sample collectors are not able to preserve samples in the field (e.g., acid preservatives are not available), the samples may be preserved in the laboratory. If preserved in the laboratory, however, samples must be held for at least 24 hours prior to analysis.
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Mercuric chloride, 6.1, Poison, UN1624
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Mercuric chloride (analyze as total mercury)
|
|---|
| SAM 2017 Method(s) |
245.1 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
125 mL
|
|---|
| Sample Container: |
Fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
28 days
|
|---|
| Preservation: |
Acidify to pH < 2 with HNO3
If sample collectors are not able to preserve samples in the field (e.g., acid preservatives are not available), the samples may be preserved in the laboratory. If preserved in the laboratory, however, samples must be held for at least 24 hours prior to analysis.
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Mercuric chloride, 6.1, Poison, UN1624
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Mercuric chloride (analyze as total mercury)
|
|---|
| SAM 2017 Method(s) |
7473 / 7471B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
28 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Mercuric chloride, 6.1, Poison, UN1624
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Mercuric chloride (analyze as total mercury)
|
|---|
| SAM 2017 Method(s) |
9102 (NIOSH) / 7473 / 7471B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
28 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Mercuric chloride, 6.1, Poison, UN1624
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Mercury, Total
|
|---|
| SAM 2017 Method(s) |
IO-5 (EPA ORD)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
Typical flow rate is 30 L/min for 12 - 24 hours
|
|---|
| Sample Container: |
Trap apparatus:
• Vapor phase: Sampling pumps specially designed for trace-level pollutant sampling; vapor phase Hg collected using two gold traps in series, attached to a fluoropolymer filter pack
• Particle phase: Glass fiber filter
|
|---|
| Holding Time: |
7 days
[Particle-phase Hg filters can be stored indefinitely at negative
(-) 40°C.]
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe the outside of apparatus clean, cap both ends. Place in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Mercury, 8, Corrosive, UN2809
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Mercury, Total
|
|---|
| SAM 2017 Method(s) |
9102 (NIOSH) / 7473 / 7471B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
28 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Mercury, 8, Corrosive, UN2809
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Mercury, Total
|
|---|
| SAM 2017 Method(s) |
7473 / 7471B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
28 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Mercury, 8, Corrosive, UN2809
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Mercury, Total
|
|---|
| SAM 2017 Method(s) |
245.1 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
125 mL
|
|---|
| Sample Container: |
Fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
28 days
|
|---|
| Preservation: |
Acidify to pH < 2 with HNO3 [If dissolved mercury is to be determined, filter the sample prior to acidification.]
If sample collectors are not able to preserve samples in the field (e.g., acid preservatives are not available), the samples may be preserved in the laboratory. If preserved in the laboratory, however, samples must be held for at least 24 hours prior to analysis.
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Mercury, 8, Corrosive, UN2809
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Mercury, Total
|
|---|
| SAM 2017 Method(s) |
245.1 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
125 mL
|
|---|
| Sample Container: |
Fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
28 days
|
|---|
| Preservation: |
Acidify to pH < 2 with HNO3 [If dissolved mercury is to be determined, filter the sample prior to acidification.]
If sample collectors are not able to preserve samples in the field (e.g., acid preservatives are not available), the samples may be preserved in the laboratory. If preserved in the laboratory, however, samples must be held for at least 24 hours prior to analysis.
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Mercury, 8, Corrosive, UN2809
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methamidophos
|
|---|
| SAM 2017 Method(s) |
J. Chromatogr. A (2007) 1154(1): 3-25
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Fluoropolymer centrifuge tube
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
Until holding time data are available, analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methamidophos
|
|---|
| SAM 2017 Method(s) |
J. Chromatogr. A (2007) 1154(1): 3-25
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth glass or fluoropolymer container with fluoropolymer-lined lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
Until holding time data are available, analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methamidophos
|
|---|
| SAM 2017 Method(s) |
538 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
• Prior to collection, add 400 µL of ammonium acetate concentrated stock and 80 µL of concentrated sodium omadine stock to sample container. [If volumes other than 40-mL are collected, the concentration of ammonium acetate and sodium omadine in the sample should be 1.5 g/L and 64 mg/L, respectively.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methamidophos
|
|---|
| SAM 2017 Method(s) |
Chromatographia (2006) 63(5/6): 223-237
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methamidophos
|
|---|
| SAM 2017 Method(s) |
J. Chromatogr. A (2007) 1154(1): 3-25
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
TBD
|
|---|
| Sample Container: |
TBD
|
|---|
| Holding Time: |
Until holding time data are available, analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film. Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methomyl
|
|---|
| SAM 2017 Method(s) |
5601 (NIOSH)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
12 - 480 L (flow rate = 0.1 - 1 L/min)
|
|---|
| Sample Container: |
Filter/solid sorbent tube:
• 13- mm quartz fiber filter
• OVS-2 tube (XAD-2 resin [270mg/140 mg])
|
|---|
| Holding Time: |
30 days if frozen; 7 days at room temperature (24°C)
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of sorbent tube clean using a damp, then dry cloth. Cap both ends of the tube with plastic caps. Place tube in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Carbamate pesticides, solid, toxic, 6.1, UN2757
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methomyl
|
|---|
| SAM 2017 Method(s) |
D7645-16 (ASTM)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
• Acidify to pH ≤ 3.8 with glacial acetic acid
• Cool to ≤ 6°C; keep from freezing
• Prior to collection of treated water samples, add 10 mg ascorbic acid to sample container
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Carbamate pesticides, liquid, toxic, 6.1, Poison, UN2992
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methomyl
|
|---|
| SAM 2017 Method(s) |
3570 / 8290A Appendix A / 8318A (EPA SW-846)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Carbamate pesticides, solid, toxic, 6.1, UN2757
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methomyl
|
|---|
| SAM 2017 Method(s) |
8318A (EPA SW-846)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Carbamate pesticides, solid, toxic, 6.1, UN2757
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methomyl
|
|---|
| SAM 2017 Method(s) |
531.2 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
28 days
|
|---|
| Preservation: |
• Prior to collection, add 0.4 g potassium dihydrogen citrate and 3.2 - 4.8 mg sodium thiosulfate to sample container
• Agitate for 1 minute after collection
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Carbamate pesticides, liquid, toxic, 6.1, Poison, UN2992
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methoxyethylmercuric acetate (analyze as total mercury)
|
|---|
| SAM 2017 Method(s) |
245.1 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
125 mL
|
|---|
| Sample Container: |
Fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
28 days
|
|---|
| Preservation: |
Acidify to pH < 2 with HNO3
If sample collectors are not able to preserve samples in the field (e.g., acid preservatives are not available), the samples may be preserved in the laboratory. If preserved in the laboratory, however, samples must be held for at least 24 hours prior to analysis
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Mercury compounds, liquid, n.o.s, 6.1, Poison, UN2024
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methoxyethylmercuric acetate (analyze as total mercury)
|
|---|
| SAM 2017 Method(s) |
IO-5 (EPA ORD)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
Typical flow rate of 30 L/min for 12 - 24 hours
|
|---|
| Sample Container: |
Trap apparatus:
• Vapor phase: Sampling pumps specially designed for trace-level pollutant sampling; vapor phase Hg collected using two gold traps in series, attached to a fluoropolymer filter pack
• Particle phase: Glass fiber filter
|
|---|
| Holding Time: |
7 days
[Particle-phase Hg filters can be stored indefinitely at negative
(-) 40°C.]
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe the outside of trap apparatus clean, cap both ends. Place in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Mercury compounds, solid, n.o.s, 6.1, Poison, UN2025
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methoxyethylmercuric acetate (analyze as total mercury)
|
|---|
| SAM 2017 Method(s) |
245.1 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
125 mL
|
|---|
| Sample Container: |
Fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
28 days
|
|---|
| Preservation: |
Acidify to pH < 2 with HNO3
If sample collectors are not able to preserve samples in the field (e.g., acid preservatives are not available), the samples may be preserved in the laboratory. If preserved in the laboratory, however, samples must be held for at least 24 hours prior to analysis.
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Mercury compounds, liquid, n.o.s, 6.1, Poison, UN2024
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methoxyethylmercuric acetate (analyze as total mercury)
|
|---|
| SAM 2017 Method(s) |
7473 / 7471B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
28 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Mercury compounds, solid, n.o.s, 6.1, Poison, UN2025
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methoxyethylmercuric acetate (analyze as total mercury)
|
|---|
| SAM 2017 Method(s) |
9102 (NIOSH) / 7473 / 7471B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
28 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Mercury compounds, solid, n.o.s, 6.1, Poison, UN2025
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methyl acrylonitrile
|
|---|
| SAM 2017 Method(s) |
524.2 / 524.3 / 524.4 (EPA OW)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw cap VOA vial with fluoropolymer-lined septum, filled with no headspace
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days with acidification; 24 hours if not acidified
|
|---|
| Preservation: |
Prior to collection of treated water samples, add 25 mg ascorbic acid to container for removal of residual chlorine
Method 524.2:
• Adjust to pH < 2 with 1:1 HCl
Methods 524.3 and 524.4:
• Adjust to pH < 2 with maleic acid
For all samples:
• If residual chlorine is > 5 mg/L, add an additional 25 mg ascorbic acid per each 5 mg/L chlorine
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Methyl acrylonitrile, 3.0, Flammable Liquid, 6.1, Poison, UN3079
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methyl acrylonitrile
|
|---|
| SAM 2017 Method(s) |
PV2004 (OSHA)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
120 L (flow rate = 1 L/min)
|
|---|
| Sample Container: |
Filter/solid sorbent tube (13- mm quartz fiber filter)
• OVS-7 tube (XAD-7 resin)
• OVS-2 (XAD-2 resin)
• OVS-SG (silica gel)
|
|---|
| Holding Time: |
13 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of sorbent tube clean using a damp, then dry cloth. Cap both ends of the tube with plastic caps. Place tube in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Methyl acrylonitrile, 3.0, Flammable Liquid, 6.1, Poison, UN3079
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methyl acrylonitrile
|
|---|
| SAM 2017 Method(s) |
3570 / 8290A Appendix A / 8260D (EPA SW-846)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Screw-cap VOA vial with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Methyl acrylonitrile, 3.0, Flammable Liquid, 6.1, Poison, UN3079
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methyl acrylonitrile
|
|---|
| SAM 2017 Method(s) |
524.2 / 524.3 / 524.4 (EPA OW)
[Tier II]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw cap VOA vial with fluoropolymer-lined septum, filled with no headspace
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days with acidification; 24 hours if not acidified
|
|---|
| Preservation: |
Prior to collection of treated water samples, add 25 mg ascorbic acid to container for removal of residual chlorine
Method 524.2:
• Adjust to pH < 2 with 1:1 HCl
Methods 524.3 and 524.4:
• Adjust to pH < 2 with maleic acid
For all samples:
• If residual chlorine is > 5 mg/L, add an additional 25 mg ascorbic acid per each 5 mg/L chlorine
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Methyl acrylonitrile, 3.0, Flammable Liquid, 6.1, Poison, UN3079
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methyl acrylonitrile
|
|---|
| SAM 2017 Method(s) |
5035A / 8260D (EPA SW-846)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
5-g coring device or amber VOA vial
AND 1 - 2 oz. glass jar (if needed to determine percent moisture)
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Coring device (If coring device is to be cleaned and reused, samples can be transferred to an amber VOA vial.)
AND glass jar (if needed to determine percent moisture)
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days if frozen;
48 hours if not frozen
|
|---|
| Preservation: |
Cool to ≤ 6°C; freeze within 48 hours to ≤ negative (-) 7°C. [Coring tools should not be frozen below -20°C.]
|
|---|
| Packaging Requirements: |
Wipe outside of coring device or container clean using a damp, then dry cloth. Place the coring device or container in a zipper bag.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Methyl acrylonitrile, 3.0, Flammable Liquid, 6.1, Poison, UN3079
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methyl fluoroacetate (analyze as fluoroacetate ion)
|
|---|
| SAM 2017 Method(s) |
J. Chromatogr. B (2010) 878: 1045-1050
[Tier III]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Until holding time data are available, analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Fluoroacetic acid, 6.1, Poison, UN2642
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methyl fluoroacetate (analyze as fluoroacetate ion)
|
|---|
| SAM 2017 Method(s) |
J. Chromatogr. A (2007) 1139: 271-278
[Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Fluoroacetic acid, 6.1, Poison, UN2642
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methyl fluoroacetate (analyze as fluoroacetate ion)
|
|---|
| SAM 2017 Method(s) |
S301-1 (NIOSH) / J. Chromatogr. A (2007) 1139: 271-278
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
Up to 480 L (flow rate = 1.5 - 2.0 L/min)
|
|---|
| Sample Container: |
Cellulose ester membrane filter/cleaned and rinsed glass or plastic bottles
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
Until holding time data are available, analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Place filter in protective covering. Place protected filter in double plastic bags, and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Fluoroacetic acid, 6.1, Poison, UN2642
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methyl fluoroacetate (analyze as fluoroacetate ion)
|
|---|
| SAM 2017 Method(s) |
J. Chromatogr. B (2010) 878: 1045-1050
[Tier III]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Until holding time data are available, analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Fluoroacetic acid, 6.1, Poison, UN2642
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methyl fluoroacetate (analyze as fluoroacetate ion)
|
|---|
| SAM 2017 Method(s) |
J. Chromatogr. A (2007) 1139: 271-278
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Fluoroacetic acid, 6.1, Poison, UN2642
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methyl hydrazine
|
|---|
| SAM 2017 Method(s) |
3541 / 3545A (EPA SW-846)
J. Chromatogr. (1993) 617: 157-162
[Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Methyl hydrazine, 6.1, Poison, UN1244
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methyl hydrazine
|
|---|
| SAM 2017 Method(s) |
3570 / 8290A Appendix A (EPA SW-846) / J. Chromatogr. (1993) 617: 157-162
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Methyl hydrazine, 6.1, Poison, UN1244
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methyl hydrazine
|
|---|
| SAM 2017 Method(s) |
J. Chromatogr. (1993) 617: 157-162
[Tier II]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Methyl hydrazine, 6.1, Poison, UN1244
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methyl hydrazine
|
|---|
| SAM 2017 Method(s) |
3510 (NIOSH)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
3 (at 0.2 ppm) - 20 L (flow rate = 0.5 to 1.5 L/min)
|
|---|
| Sample Container: |
Bubbler (0.1 M HCl). Seal and transfer the bubbler to container for shipping.
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
5 days
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Methyl hydrazine, 6.1, Poison, UN1244
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methyl hydrazine
|
|---|
| SAM 2017 Method(s) |
J. Chromatogr. (1993) 617: 157-162
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Methyl hydrazine, 6.1, Poison, UN1244
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methyl isocyanate
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Methyl isocyanate
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Methyl isocyanate
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Methyl isocyanate
|
|---|
| SAM 2017 Method(s) |
OSHA 54 [Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
15 L (flow rate = 0.05 L/min)
|
|---|
| Sample Container: |
Solid sorbent tube (XAD-7 tubes coated with 0.03 mg of 1-(2-pyridyl)piperazine
|
|---|
| Holding Time: |
18 days
|
|---|
| Preservation: |
• Cool to ≤ 6°C
• Protect from light
|
|---|
| Packaging Requirements: |
Wipe outside of tube clean using a damp, then dry cloth. Cap ends of tube, wrap tube with OSHA seal, and place in container. Seal the container with non-reactive tape or film. Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Methyl isocyanate, 6.1, Poison, UN2480
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methyl isocyanate
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Methyl paraoxon
|
|---|
| SAM 2017 Method(s) |
3535A / 8270E (EPA SW-846)
[Tier III]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methyl paraoxon
|
|---|
| SAM 2017 Method(s) |
3535A / 8270E (EPA SW-846)
[Tier III]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methyl paraoxon
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methyl paraoxon
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methyl paraoxon
|
|---|
| SAM 2017 Method(s) |
TO-10A (EPA ORD)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
240 - 7200 L (flow rate = 1 - 5 L/min)
|
|---|
| Sample Container: |
Sorbent cartridge containing PUF or PUF in combination with other solid sorbent
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Remove PUF cartridge from sampler, wrap with aluminum foil used to store cartridge, and place in a sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methyl parathion
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methyl parathion
|
|---|
| SAM 2017 Method(s) |
TO-10A (EPA ORD)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
240 - 7200 L (flow rate = 1 - 5 L/min)
|
|---|
| Sample Container: |
Sorbent cartridge containing PUF or PUF in combination with other solid sorbent
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Remove PUF cartridge from sampler, wrap with aluminum foil used to store cartridge, and place in a sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methyl parathion
|
|---|
| SAM 2017 Method(s) |
3535A / 8270E (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methyl parathion
|
|---|
| SAM 2017 Method(s) |
3535A / 8270E (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methyl parathion
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methylamine
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Methylamine
|
|---|
| SAM 2017 Method(s) |
OSHA 40 [Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
10 L (flow rate = 0.2 L/min)
|
|---|
| Sample Container: |
Solid sorbent tubes containing XAD-7 resin coated with 10% NBD chloride (7-chloro-4-nitrobenzo-2-oxa-1,3-diazole) by weight
|
|---|
| Holding Time: |
15 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of tube clean using a damp, then dry cloth. Cap ends of tube, wrap tube with OSHA seal, and place in container. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND, Methylamine, anhydrous, 2.1, Flammable gas, UN1061
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methylamine
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Methylamine
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Methylamine
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Methylphosphonic acid (MPA) (degradation product of VX, GB, & GD)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-13/224 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus compound, toxic, solid, n.o.s, 6.1, Poison, UN3464
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methylphosphonic acid (MPA) (degradation product of VX, GB, & GD)
|
|---|
| SAM 2017 Method(s) |
D7597-16 (ASTM)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
24 hours
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus compound, toxic, liquid, n.o.s, 6.1, Poison, UN3278
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methylphosphonic acid (MPA) (degradation product of VX, GB, & GD)
|
|---|
| SAM 2017 Method(s) |
TO-10A (EPA ORD)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
240 - 7200 L (flow rate = 1 - 5 L/min)
|
|---|
| Sample Container: |
Sorbent cartridge containing PUF or PUF in combination with other solid sorbent
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Remove PUF cartridge from sampler, wrap with aluminum foil used to store cartridge, and place in a sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus compound, toxic, solid, n.o.s, 6.1, Poison, UN3464
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methylphosphonic acid (MPA) (degradation product of VX, GB, & GD)
|
|---|
| SAM 2017 Method(s) |
E2866-12 (ASTM)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus compound, toxic, solid, n.o.s, 6.1, Poison, UN3464
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Methylphosphonic acid (MPA) (degradation product of VX, GB, & GD)
|
|---|
| SAM 2017 Method(s) |
D7597-16 (ASTM)
[Tier III]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
24 hours
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus compound, toxic, liquid, n.o.s, 6.1, Poison, UN3278
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Mevinphos
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Mevinphos
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Mevinphos
|
|---|
| SAM 2017 Method(s) |
525.3 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Method 525.2:
• Add sodium sulfite to empty sample container to remove residual chlorine from treated water samples [Sodium sulfite can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: for a 1-L sample, add 40 - 50 mg sodium sulfite (1.6 - 2 mg/40-mL sample).]
• Acidify to pH < 2 with 1:1 HCl
• Cool to ≤ 6°C; keep from freezing
Method 525.3 (to empty sample container):
• Add 4 mg ascorbic acid to remove residual chlorine from treated water samples
• Add 14 mg trisodium EDTA, and 400 mg potassium dihydrogen citrate
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Mevinphos
|
|---|
| SAM 2017 Method(s) |
TO-10A (EPA ORD)
[Tier II]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
240 - 7200 L (flow rate = 1 - 5 L/min)
|
|---|
| Sample Container: |
Sorbent cartridge containing PUF or PUF in combination with other solid sorbent
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Remove PUF cartridge from sampler, wrap with aluminum foil used to store cartridge, and place in a sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Mevinphos
|
|---|
| SAM 2017 Method(s) |
3535A / 8270E (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Monocrotophos
|
|---|
| SAM 2017 Method(s) |
3541 / 3545A / 8270E (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Monocrotophos
|
|---|
| SAM 2017 Method(s) |
3535A / 8270E (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Monocrotophos
|
|---|
| SAM 2017 Method(s) |
3535A / 8270E (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Monocrotophos
|
|---|
| SAM 2017 Method(s) |
TO-10A (EPA ORD)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
240 - 7200 L (flow rate = 1 - 5 L/min)
|
|---|
| Sample Container: |
Sorbent cartridge containing PUF or PUF in combination with other solid sorbent
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Remove PUF cartridge from sampler, wrap with aluminum foil used to store cartridge, and place in a sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Monocrotophos
|
|---|
| SAM 2017 Method(s) |
3570 / 8290 Appendix A / 8270E (EPA SW-846)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Mustard, nitrogen (HN-1)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-12/653 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or
1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap containers with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Mustard, nitrogen (HN-1)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-12/653 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Mustard, nitrogen (HN-1)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-12/653 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap containers with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Mustard, nitrogen (HN-1)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-12/653 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Mustard, nitrogen (HN-1)
|
|---|
| SAM 2017 Method(s) |
TO-17 (EPA ORD)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
1 - 4 L (flow rate = 16 - 67 mL/min)
|
|---|
| Sample Container: |
Stainless steel, 3.5-inch long tubes with a 6-cm sorbent bed and 1/4-inch o.d.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wrap tube in aluminum foil, and place in a clean sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Mustard, nitrogen (HN-2)
|
|---|
| SAM 2017 Method(s) |
TO-17 (EPA ORD)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
1 - 4 L (flow rate = 16 - 67 mL/min)
|
|---|
| Sample Container: |
Stainless steel, 3.5-inch long tubes with a 6-cm sorbent bed and 1/4-inch o.d.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wrap tube in aluminum foil, and place in a clean sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Mustard, nitrogen (HN-2)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-12/653 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap containers with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Mustard, nitrogen (HN-2)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-12/653 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap containers with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Mustard, nitrogen (HN-2)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-12/653 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Mustard, nitrogen (HN-2)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-12/653 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Mustard, nitrogen (HN-3)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-12/653 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Mustard, nitrogen (HN-3)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-12/653 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Mustard, nitrogen (HN-3)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-12/653 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap containers with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Mustard, nitrogen (HN-3)
|
|---|
| SAM 2017 Method(s) |
TO-17 (EPA ORD)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
1 - 4 L (flow rate = 16 - 67 mL/min)
|
|---|
| Sample Container: |
Stainless steel, 3.5-inch long tubes with a 6-cm sorbent bed and 1/4-inch o.d.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wrap tube in aluminum foil, and place in a clean sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Mustard, nitrogen (HN-3)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-12/653 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or
1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap containers with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Mustard, sulfur (HD)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/115 (EPA NHSRC)
[Tier I]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap containers with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Mustard, sulfur (HD)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/115 (EPA NHSRC)
[Tier I]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap containers with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Mustard, sulfur (HD)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/115 (EPA NHSRC)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Mustard, sulfur (HD)
|
|---|
| SAM 2017 Method(s) |
TO-17 (EPA ORD)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
1 - 4 L (flow rate = 16 - 67 mL/min)
|
|---|
| Sample Container: |
Stainless steel, 3.5-inch long tubes with a 6-cm sorbent bed and 1/4-inch o.d.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wrap tube in aluminum foil, and place in a clean sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Mustard, sulfur (HD)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/115 (EPA NHSRC)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
N-Ethyldiethanolamine (EDEA) (degradation product of HN-1)
|
|---|
| SAM 2017 Method(s) |
3509 (NIOSH)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
0.5 - 300 L (flow rate = 0.5 - 1 L/min)
|
|---|
| Sample Container: |
Impinger (15 mL 2 mM hexanesulfonic acid).
[Impinger contents are transferred into VOA vial for shipping.]
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
21 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film, and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Ethanolamine solutions, 8, Corrosive, UN2491
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
N-Ethyldiethanolamine (EDEA) (degradation product of HN-1)
|
|---|
| SAM 2017 Method(s) |
D7599-16 (ASTM)
[Tier III]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Ethanolamine solutions, 8, Corrosive, UN2491
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
N-Ethyldiethanolamine (EDEA) (degradation product of HN-1)
|
|---|
| SAM 2017 Method(s) |
D7599-16 (ASTM)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Ethanolamine solutions, 8, Corrosive, UN2491
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
N-Ethyldiethanolamine (EDEA) (degradation product of HN-1)
|
|---|
| SAM 2017 Method(s) |
3541 / 3545A (EPA SW-846) / EPA/600/R-11/143 (EPA NHSRC/CDC)
[SAM Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Ethanolamine solutions, 8, Corrosive, UN2491
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
N-Ethyldiethanolamine (EDEA) (degradation product of HN-1)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-11/123 (EPA NHSRC/CDC)
[Tier II]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
125 mL polypropylene container with a polypropylene screw cap
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
28 days
|
|---|
| Preservation: |
• Cool to ≤ 6°C
• Protect from light
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Ethanolamine solutions, 8, Corrosive, UN2491
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
N-Methyl diethanolamine (MDEA) (degradation product of HN-2)
|
|---|
| SAM 2017 Method(s) |
3541 / 3545A (EPA SW-846) / EPA/600/R-11/123 (EPA NHSRC/CDC)
[Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Ethanolamine solutions, 8, Corrosive, UN2491
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
N-Methyl diethanolamine (MDEA) (degradation product of HN-2)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-11/123 (EPA NHSRC/CDC)
[Tier II]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
125 mL polypropylene container with a polypropylene screw cap
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
28 days
|
|---|
| Preservation: |
• Cool to ≤ 6°C
• Protect from light
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Ethanolamine solutions, 8, Corrosive, UN2491
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
N-Methyl diethanolamine (MDEA) (degradation product of HN-2)
|
|---|
| SAM 2017 Method(s) |
D7599-16 (ASTM)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Ethanolamine solutions, 8, Corrosive, UN2491
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
N-Methyl diethanolamine (MDEA) (degradation product of HN-2)
|
|---|
| SAM 2017 Method(s) |
D7599-16 (ASTM)
[Tier III]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Ethanolamine solutions, 8, Corrosive, UN2491
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
N-Methyl diethanolamine (MDEA) (degradation product of HN-2)
|
|---|
| SAM 2017 Method(s) |
3509 (NIOSH)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
0.5 - 300 L (flow rate = 0.5 - 1 L/min)
|
|---|
| Sample Container: |
Impinger (15 mL 2 mM hexanesulfonic acid)
[Impinger contents are transferred into VOA vial for shipping.]
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
21 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Ethanolamine solutions, 8, Corrosive, UN2491
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Nicotine compounds (analyze as nicotine)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Nicotine compounds, solid, n.o.s, 6.1, Poison, UN1655
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Nicotine compounds (analyze as nicotine)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Nicotine compounds, solid, n.o.s, 6.1, Poison, UN1655
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Nicotine compounds (analyze as nicotine)
|
|---|
| SAM 2017 Method(s) |
3535A / 8270E (EPA SW-846)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Nicotine compounds, liquid, n.o.s, 6.1, Poison, UN3144
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Nicotine compounds (analyze as nicotine)
|
|---|
| SAM 2017 Method(s) |
3535A / 8270E (EPA SW-846)
[Tier II]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Nicotine compounds, liquid, n.o.s, 6.1, Poison, UN3144
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Nicotine compounds (analyze as nicotine)
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX)
|
|---|
| SAM 2017 Method(s) |
3535A / 8330B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND HMX, 1.1, Explosive, UN0391
Samples containing secondary explosives at concentrations less than 10% by weight (100,000 mg/kg) or primary explosives at concentrations less than 2% can be sent as normal environmental samples. Consult laboratory on specifics regarding shipping label and shipping requirements for samples with concentrations greater than these amounts.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX)
|
|---|
| SAM 2017 Method(s) |
3535A / 8330B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND HMX, 1.1, Explosive, UN0391
Samples containing secondary explosives at concentrations less than 10% by weight (100,000 mg/kg) or primary explosives at concentrations less than 2% can be sent as normal environmental samples. Consult laboratory on specifics regarding shipping label and shipping requirements for samples with concentrations greater than these amounts.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX)
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX)
|
|---|
| SAM 2017 Method(s) |
8330B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND HMX, 1.1 Explosive, UN0391
Samples containing secondary explosives at concentrations less than 10% by weight (100,000 mg/kg) or primary explosives at concentrations less than 2% can be sent as normal environmental samples. Consult laboratory on specifics regarding shipping label and shipping requirements for samples with concentrations greater than these amounts.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX)
|
|---|
| SAM 2017 Method(s) |
3570 / 8290 Appendix A / 8330B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND HMX, 1.1, Explosive, UN0391
Samples containing secondary explosives at concentrations less than 10% by weight (100,000 mg/kg) or primary explosives at concentrations less than 2% can be sent as normal environmental samples. Consult laboratory on specifics regarding shipping label and shipping requirements for samples with concentrations greater than these amounts.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Osmium tetraoxide (analyze for total osmium)
|
|---|
| SAM 2017 Method(s) |
3015A / 6010D/6020B (EPA SW-846)
[Tier II]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
125 mL
|
|---|
| Sample Container: |
Glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
6 months with acidification. Samples must be acidified within 14 days of collection.
|
|---|
| Preservation: |
1% NH4OH
If sample collectors are not able to preserve samples in the field (e.g., acid preservatives are not available), the samples may be preserved in the laboratory. If preserved in the laboratory, however, samples must be held for at least 24 hours prior to analysis.
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Osmium tetroxide, 6.1, Poison, UN2471
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Osmium tetraoxide (analyze for total osmium)
|
|---|
| SAM 2017 Method(s) |
3051A / 6010D/6020B (EPA SW-846)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth fluoropolymer or glass container with fluoropolymer-lined lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Osmium tetroxide, 6.1, Poison, UN2471
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Osmium tetraoxide (analyze for total osmium)
|
|---|
| SAM 2017 Method(s) |
3051A / 6010D/6020B (EPA SW-846)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth fluoropolymer or glass container with fluoropolymer-lined lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Osmium tetroxide, 6.1, Poison, UN2471
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Osmium tetraoxide (analyze for total osmium)
|
|---|
| SAM 2017 Method(s) |
3015A / 6010D/6020B (EPA SW-846)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
125 mL
|
|---|
| Sample Container: |
Glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
6 months with acidification. Samples must be acidified within 14 days of collection.
|
|---|
| Preservation: |
1% NH4OH
If sample collectors are not able to preserve samples in the field (e.g., acid preservatives are not available), the samples may be preserved in the laboratory. If preserved in the laboratory, however, samples must be held for at least 24 hours prior to analysis.
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Osmium tetroxide, 6.1, Poison, UN2471
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Osmium tetraoxide (analyze for total osmium)
|
|---|
| SAM 2017 Method(s) |
IO-3.1 / IO-3.4 (EPA ORD)
[Tier II]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
Up to 1700 m3
|
|---|
| Sample Container: |
Filter (quartz, silica or cellulose fiber)
|
|---|
| Holding Time: |
Until holding time data are available, analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Place filter in protective covering. Place protected filter in double plastic bags, and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Osmium tetroxide, 6.1, Poison, UN2471
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Oxamyl
|
|---|
| SAM 2017 Method(s) |
5601 (NIOSH)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
240 - 480 L (flow rate = 0.1 - 1 L/min)
|
|---|
| Sample Container: |
Filter/solid sorbent tube (OVS-2 tube: 13 mm quartz fiber filter, XAD-2 [270mg/140 mg])
|
|---|
| Holding Time: |
30 days if frozen; 7 days at room temperature (24°C)
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of sorbent tube clean using a damp, then dry cloth. Cap both ends of the tube with plastic caps. Place tube in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Carbamate pesticides, solid, toxic, 6.1, UN2757
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Oxamyl
|
|---|
| SAM 2017 Method(s) |
531.2 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
28 days
|
|---|
| Preservation: |
• Prior to collection, add 0.4 g potassium dihydrogen citrate and 3.2 - 4.8 mg sodium thiosulfate to sample container
• Agitate for 1 minute after collection
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Carbamate pesticides, liquid, toxic, 6.1, Poison, UN2992
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Oxamyl
|
|---|
| SAM 2017 Method(s) |
8318A (EPA SW-846)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Carbamate pesticides, solid, toxic, 6.1, UN2757
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Oxamyl
|
|---|
| SAM 2017 Method(s) |
D7645-16 (ASTM)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
• Acidify to pH ≤ 3.8 with glacial acetic acid
• Cool to ≤ 6°C; keep from freezing
• Prior to collection of treated water samples, add 10 mg ascorbic acid to sample container
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Carbamate pesticides, liquid, toxic, 6.1, Poison, UN2992
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Oxamyl
|
|---|
| SAM 2017 Method(s) |
3570 / 8290 Appendix A / 8318A (EPA SW-846)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Carbamate pesticides, solid, toxic, 6.1, UN2757
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Paraoxon
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Paraoxon
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Paraoxon
|
|---|
| SAM 2017 Method(s) |
TO-10A (EPA ORD)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
240 - 7200 L (flow rate = 1 - 5 L/min)
|
|---|
| Sample Container: |
Sorbent cartridge containing PUF or PUF in combination with other solid sorbent
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Remove PUF cartridge from sampler, wrap with aluminum foil used to store cartridge, and place in a sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Paraoxon
|
|---|
| SAM 2017 Method(s) |
3520C / 3535A / 8270E (EPA SW-846)
[Tier III]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Paraoxon
|
|---|
| SAM 2017 Method(s) |
3520C / 3535A / 8270E (EPA SW-846)
[Tier III]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Paraquat
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Paraquat
|
|---|
| SAM 2017 Method(s) |
J. Chromatogr. A (2008) 1196-1197:110-116
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Bipyridilium pesticides, Solid, 6.1, Toxic, UN2811
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Paraquat
|
|---|
| SAM 2017 Method(s) |
J. Chromatogr. A (2008) 1196-1197:110-116
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Bipyridilium pesticides, Solid, 6.1, Toxic, UN2811
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Paraquat
|
|---|
| SAM 2017 Method(s) |
549.2 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
250 mL
|
|---|
| Sample Container: |
High density PVC or silanized amber glass bottle fitted with screw cap
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add 100 mg/L sodium thiosulfate to remove residual chlorine from treated water samples
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Bipyridilium pesticides, liquid, 6.1, Toxic, UN3016
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Paraquat
|
|---|
| SAM 2017 Method(s) |
549.2 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
250 mL
|
|---|
| Sample Container: |
High density PVC or silanized amber glass bottle fitted with screw cap
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add 100 mg/L sodium thiosulfate to remove residual chlorine from treated water samples
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Bipyridilium pesticides, liquid, 6.1, Toxic, UN3016
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Parathion
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Parathion
|
|---|
| SAM 2017 Method(s) |
3520C / 3535A / 8270E (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Parathion
|
|---|
| SAM 2017 Method(s) |
3520C / 3535A / 8270E (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Parathion
|
|---|
| SAM 2017 Method(s) |
TO-10A (EPA ORD)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
240 - 7200 L (flow rate = 1 - 5 L/min)
|
|---|
| Sample Container: |
Sorbent cartridge containing PUF or PUF in combination with other solid sorbent
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Remove PUF cartridge from sampler, wrap with aluminum foil used to store cartridge, and place in a sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Parathion
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Pentaerythritol tetranitrate (PETN)
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Pentaerythritol tetranitrate (PETN)
|
|---|
| SAM 2017 Method(s) |
3535A / 8330B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND PETN, 1.1, Explosive, UN0411
Samples containing secondary explosives at concentrations less than 10% by weight (100,000 mg/kg) or primary explosives at concentrations less than 2% can be sent as normal environmental samples. Consult laboratory on specifics regarding shipping label and shipping requirements for samples with concentrations greater than these amounts.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Pentaerythritol tetranitrate (PETN)
|
|---|
| SAM 2017 Method(s) |
3535A / 8330B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND PETN, 1.1, Explosive, UN0411
Samples containing secondary explosives at concentrations less than 10% by weight (100,000 mg/kg) or primary explosives at concentrations less than 2% can be sent as normal environmental samples. Consult laboratory on specifics regarding shipping label and shipping requirements for samples with concentrations greater than these amounts.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Pentaerythritol tetranitrate (PETN)
|
|---|
| SAM 2017 Method(s) |
8330B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND PETN, 1.1 Explosive, UN0411
Samples containing secondary explosives at concentrations less than 10% by weight (100,000 mg/kg) or primary explosives at concentrations less than 2% can be sent as normal environmental samples. Consult laboratory on specifics regarding shipping label and shipping requirements for samples with concentrations greater than these amounts.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Pentaerythritol tetranitrate (PETN)
|
|---|
| SAM 2017 Method(s) |
3570 / 8290A Appendix A / 8330B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND PETN, 1.1 , Explosive, UN0411
Samples containing secondary explosives at concentrations less than 10% by weight (100,000 mg/kg) or primary explosives at concentrations less than 2% can be sent as normal environmental samples. Consult laboratory on specifics regarding shipping label and shipping requirements for samples with concentrations greater than these amounts.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Phencyclidine
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
• Cool to ≤ 6°C; keep from freezing
For treated water samples:
Preservatives/dechlorinating agents not required, but the analyte is not affected by the following, if added to address other analytes:
• Sodium sulfite
• 1.6 - 2.0 mg NH4Cl
[Sodium sulfite can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: for a 1-L sample, add 40 - 50 mg sodium sulfite (1.6 - 2 mg/40-mL sample).]
For all other samples:
• Can be adjusted to pH < 2 with 1:1 HCl, but this is not required
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Phencyclidine
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Phencyclidine
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
• Cool to ≤ 6°C; keep from freezing
For treated water samples:
Preservatives/dechlorinating agents not required, but the analyte is not affected by the following, if added to address other analytes:
• Sodium sulfite
• 1.6 - 2.0 mg NH4Cl
[Sodium sulfite can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: for a 1-L sample, add 40 - 50 mg sodium sulfite (1.6 - 2 mg/40-mL sample).]
For all other samples:
• Can be adjusted to pH < 2 with 1:1 HCl, but this is not required
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Phencyclidine
|
|---|
| SAM 2017 Method(s) |
9106 / 9109 [NIOSH]
(Tier II)
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
30 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Phencyclidine
|
|---|
| SAM 2017 Method(s) |
TO-10A (EPA ORD)
[Tier II]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
240 - 7200 L (flow rate = 1 - 5 L/min)
|
|---|
| Sample Container: |
Sorbent cartridge containing PUF or PUF in combination with other solid sorbent
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Remove PUF cartridge from sampler, wrap with aluminum foil used to store cartridge, and place in a sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Phorate
|
|---|
| SAM 2017 Method(s) |
3535A / 8270E (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Phorate
|
|---|
| SAM 2017 Method(s) |
TO-10A (EPA ORD)
[Tier II]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
240 - 7200 L (flow rate = 1 - 5 L/min)
|
|---|
| Sample Container: |
Sorbent cartridge containing PUF or PUF in combination with other solid sorbent
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Remove PUF cartridge from sampler, wrap with aluminum foil used to store cartridge, and place in a sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Phorate
|
|---|
| SAM 2017 Method(s) |
3535A / 8270E (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Phorate
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Phorate
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Phorate sulfone
|
|---|
| SAM 2017 Method(s) |
540 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
250 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
28 days
|
|---|
| Preservation: |
Add the following to sample containers prior to collection:
• 100 mg/L solid ascorbic acid (for removal of residual chlorine from treated water samples)
• 2 g/L 2-chloroacetamide (antimicrobial preservative)
• 7.75 g/L Trizma© base (buffering agent)
After collecting the sample:
• Cap the container and agitate until preservative is dissolved
• Cool to ≤10°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Phorate sulfone
|
|---|
| SAM 2017 Method(s) |
540 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
250 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
28 days
|
|---|
| Preservation: |
Add the following to sample containers prior to collection:
• 100 mg/L solid ascorbic acid (for removal of residual chlorine from treated water samples)
• 2 g/L 2-chloroacetamide (antimicrobial preservative)
• 7.75 g/L Trizma© base (buffering agent)
After collecting the sample:
• Cap the container and agitate until preservative is dissolved
• Cool to ≤10°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Phorate sulfone
|
|---|
| SAM 2017 Method(s) |
TO-10A (EPA ORD)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
240 - 7200 L (flow rate = 1 - 5 L/min)
|
|---|
| Sample Container: |
Sorbent cartridge containing PUF or PUF in combination with other solid sorbent
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Remove PUF cartridge from sampler, wrap with aluminum foil used to store cartridge, and place in a sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Phorate sulfone
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Phorate sulfone
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Phorate sulfone oxon
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Phorate sulfone oxon
|
|---|
| SAM 2017 Method(s) |
540 (EPA OW)
[Tier III]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
250 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
28 days
|
|---|
| Preservation: |
Add the following to sample containers prior to collection:
• 100 mg/L solid ascorbic acid (for removal of residual chlorine from treated water samples)
• 2 g/L 2-chloroacetamide (antimicrobial preservative)
• 7.75 g/L Trizma© base (buffering agent)
After collecting the sample:
• Cap the container and agitate until preservative is dissolved
• Cool to ≤10°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Phorate sulfone oxon
|
|---|
| SAM 2017 Method(s) |
540 (EPA OW)
[Tier III]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
250 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
28 days
|
|---|
| Preservation: |
Add the following to sample containers prior to collection:
• 100 mg/L solid ascorbic acid (for removal of residual chlorine from treated water samples)
• 2 g/L 2-chloroacetamide (antimicrobial preservative)
• 7.75 g/L Trizma© base (buffering agent)
After collecting the sample:
• Cap the container and agitate until preservative is dissolved
• Cool to ≤10°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Phorate sulfone oxon
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Phorate sulfone oxon
|
|---|
| SAM 2017 Method(s) |
TO-10A (EPA ORD)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
240 - 7200 L (flow rate = 1 - 5 L/min)
|
|---|
| Sample Container: |
Sorbent cartridge containing PUF or PUF in combination with other solid sorbent
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Remove PUF cartridge from sampler, wrap with aluminum foil used to store cartridge, and place in a sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Phorate sulfoxide
|
|---|
| SAM 2017 Method(s) |
540 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
250 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
28 days
|
|---|
| Preservation: |
Add the following to sample containers prior to collection:
• 100 mg/L solid ascorbic acid (for removal of residual chlorine from treated water samples)
• 2 g/L 2-chloroacetamide (antimicrobial preservative)
• 7.75 g/L Trizma© base (buffering agent)
After collecting the sample:
• Cap the container and agitate until preservative is dissolved
• Cool to ≤10°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Phorate sulfoxide
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Phorate sulfoxide
|
|---|
| SAM 2017 Method(s) |
540 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
250 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
28 days
|
|---|
| Preservation: |
Add the following to sample containers prior to collection:
• 100 mg/L solid ascorbic acid (for removal of residual chlorine from treated water samples)
• 2 g/L 2-chloroacetamide (antimicrobial preservative)
• 7.75 g/L Trizma© base (buffering agent)
After collecting the sample:
• Cap the container and agitate until preservative is dissolved
• Cool to ≤10°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Phorate sulfoxide
|
|---|
| SAM 2017 Method(s) |
TO-10A (EPA ORD)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
240 - 7200 L (flow rate = 1 - 5 L/min)
|
|---|
| Sample Container: |
Sorbent cartridge containing PUF or PUF in combination with other solid sorbent
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Remove PUF cartridge from sampler, wrap with aluminum foil used to store cartridge, and place in a sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Phorate sulfoxide
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Phorate sulfoxide oxon
|
|---|
| SAM 2017 Method(s) |
TO-10A (EPA ORD)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
240 - 7200 L (flow rate = 1 - 5 L/min)
|
|---|
| Sample Container: |
Sorbent cartridge containing PUF or PUF in combination with other solid sorbent
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Remove PUF cartridge from sampler, wrap with aluminum foil used to store cartridge, and place in a sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Phorate sulfoxide oxon
|
|---|
| SAM 2017 Method(s) |
540 (EPA OW)
[Tier III]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
250 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
28 days
|
|---|
| Preservation: |
Add the following to sample containers prior to collection:
• 100 mg/L solid ascorbic acid (for removal of residual chlorine from treated water samples)
• 2 g/L 2-chloroacetamide (antimicrobial preservative)
• 7.75 g/L Trizma© base (buffering agent)
After collecting the sample:
• Cap the container and agitate until preservative is dissolved
• Cool to ≤10°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Phorate sulfoxide oxon
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Phorate sulfoxide oxon
|
|---|
| SAM 2017 Method(s) |
540 (EPA OW)
[Tier III]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
250 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
28 days
|
|---|
| Preservation: |
Add the following to sample containers prior to collection:
• 100 mg/L solid ascorbic acid (for removal of residual chlorine from treated water samples)
• 2 g/L 2-chloroacetamide (antimicrobial preservative)
• 7.75 g/L Trizma© base (buffering agent)
After collecting the sample:
• Cap the container and agitate until preservative is dissolved
• Cool to ≤10°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Phorate sulfoxide oxon
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Phosgene
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Phosgene
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Phosgene
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Phosgene
|
|---|
| SAM 2017 Method(s) |
OSHA 61
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
240 L (flow rate = 1 L/min)
|
|---|
| Sample Container: |
Silane-treated glass tubes [4-mm i.d. x 6-mm o.d. x 11-cm long, and packed with 150 mg/75 mg of pretreated XAD-2 adsorbent coated with 2-HMP (2-[hydroxymethyl] piperidine)]
|
|---|
| Holding Time: |
19 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of tube clean using a damp, then dry cloth. Cap ends of tube, wrap tube with OSHA seal, and place in an air tight container containing activated carbon. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Phosgene, 2.3, Poisonous gas, UN1076
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Phosgene
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Phosphamidon
|
|---|
| SAM 2017 Method(s) |
525.3 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Method 525.2:
• Add sodium sulfite to empty sample container to remove residual chlorine from treated water samples [Sodium sulfite can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: for a 1-L sample, add 40 - 50 mg sodium sulfite (1.6 - 2 mg/40-mL sample).]
• Acidify to pH < 2 with 1:1 HCl
• Cool to ≤ 6°C; keep from freezing
Method 525.3 (to empty sample container):
• Add 4 mg ascorbic acid to remove residual chlorine from treated water samples
• Add 14 mg trisodium EDTA, and 400 mg potassium dihydrogen citrate
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Phosphamidon
|
|---|
| SAM 2017 Method(s) |
TO-10A (EPA ORD)
[Tier II]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
240 - 7200 L (flow rate = 1 - 5 L/min)
|
|---|
| Sample Container: |
Sorbent cartridge containing PUF or PUF in combination with other solid sorbent
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Remove PUF cartridge from sampler, wrap with aluminum foil used to store cartridge, and place in a sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Phosphamidon
|
|---|
| SAM 2017 Method(s) |
3520C / 3535A / 8270E (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Phosphamidon
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Phosphamidon
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Phosphine
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Phosphine
|
|---|
| SAM 2017 Method(s) |
6002 (NIOSH)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
1 (at 0.3 ppm) - 16 L (flow rate = 0.01 - 0.2 L/min)
|
|---|
| Sample Container: |
Sorbent tube (Hg(CN)2 coated silica gel [300 mg/150 mg])
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of sorbent tube clean using a damp, then dry cloth. Cap tubes with plastic (not rubber) caps. Place tubes in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Phosphine, 2.3, Poisonous gas, UN2199
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Phosphine
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Phosphine
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Phosphine
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Phosphorus trichloride
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Phosphorus trichloride
|
|---|
| SAM 2017 Method(s) |
6402 (NIOSH)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
11 (at 0.5 ppm) - 100 L (flow rate = 0.05 - 0.2 L/min)
|
|---|
| Sample Container: |
Bubbler (15 mL H2O)
Seal and transfer the bubbler to container for shipping.
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
Until holding time data are available, analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of ontainer clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap each glass container with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Phosphorus trichloride, 6.1, Poison, UN1809
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Phosphorus trichloride
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Phosphorus trichloride
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Phosphorus trichloride
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Pinacolyl methyl phosphonic acid (PMPA) (degradation product of GD)
|
|---|
| SAM 2017 Method(s) |
D7597-16 (ASTM)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
24 hours
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus compound, toxic, liquid, n.o.s, 6.1, Poison, UN3278
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Pinacolyl methyl phosphonic acid (PMPA) (degradation product of GD)
|
|---|
| SAM 2017 Method(s) |
E2866-12 (ASTM)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus compound, toxic, solid, n.o.s, 6.1, Poison, UN3464
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Pinacolyl methyl phosphonic acid (PMPA) (degradation product of GD)
|
|---|
| SAM 2017 Method(s) |
D7597-16 (ASTM)
[Tier III]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
24 hours
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus compound, toxic, liquid, n.o.s, 6.1, Poison, UN3278
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Pinacolyl methyl phosphonic acid (PMPA) (degradation product of GD)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-13/224 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus compound, toxic, solid, n.o.s, 6.1, Poison, UN3464
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Pinacolyl methyl phosphonic acid (PMPA) (degradation product of GD)
|
|---|
| SAM 2017 Method(s) |
TO-10A (EPA ORD)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
240 - 7200 L (flow rate = 1 - 5 L/min)
|
|---|
| Sample Container: |
Sorbent cartridge containing PUF or PUF in combination with other solid sorbent
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Remove PUF cartridge from sampler, wrap with aluminum foil used to store cartridge, and place in a sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus compound, toxic, solid, n.o.s, 6.1, Poison, UN3464
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Propylene oxide
|
|---|
| SAM 2017 Method(s) |
1612 (NIOSH)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
0.5 (at 100 ppm) - 5 L (flow rate = 0.01 - 0.2 L/min)
|
|---|
| Sample Container: |
Solid sorbent tube (coconut shell charcoal [100 mg/50 mg])
|
|---|
| Holding Time: |
6 weeks if frozen;
7 days if not frozen
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of sorbent tube clean using a damp, then dry cloth. Cap tubes with plastic (not rubber) caps. Place tubes in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Propylene oxide, 3, Flammable, UN1280.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Propylene oxide
|
|---|
| SAM 2017 Method(s) |
5030C / 8260D (EPA SW-846)
[Tier II]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw cap VOA vial with fluoropolymer-lined septum, filled with no headspace
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days with acidification; 7 days if not acidified
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Adjust to pH < 2 with 1:1 HCl
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Propylene oxide, 3, Flammable liquid, UN1280
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Propylene oxide
|
|---|
| SAM 2017 Method(s) |
5030C / 8260D (EPA SW-846)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw cap VOA vial with fluoropolymer-lined septum, filled with no headspace
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days with acidification; 7 days if not acidified
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Adjust to pH < 2 with 1:1 HCl
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Propylene oxide, 3, Flammable liquid, UN1280
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Propylene oxide
|
|---|
| SAM 2017 Method(s) |
5035A / 8260D (EPA SW-846)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
5-g coring device or amber VOA vial
AND 1 - 2 oz. glass jar (if needed to determine percent moisture)
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Coring device (If coring device is to be cleaned and reused, samples can be transferred to an amber VOA vial.)
AND glass jar (if needed to determine percent moisture)
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days if frozen;
48 hours if not frozen
|
|---|
| Preservation: |
Cool to ≤ 6°C; freeze within 48 hours to ≤ negative (-) 7°C [Coring tools should not be frozen below -20°C.]
|
|---|
| Packaging Requirements: |
Wipe outside of coring device or container clean using a damp, then dry cloth. Place the coring device or container in a zipper bag.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Propylene oxide, 3, Flammable, UN1280
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Propylene oxide
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
R-33 (VR) [methylphosphonothioic acid, S-[2-(diethylamino)ethyl]O-2-methylpropyl ester]
|
|---|
| SAM 2017 Method(s) |
TO-17 (EPA ORD)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
1 - 4 L (flow rate = 16 - 67 mL/min)
|
|---|
| Sample Container: |
Stainless steel, 3.5-inch long tubes with a 6-cm sorbent bed and 1/4-inch o.d.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wrap tube in aluminum foil, and place in a clean sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
R-33 (VR) [methylphosphonothioic acid, S-[2-(diethylamino)ethyl]O-2-methylpropyl ester]
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-12/653 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Cool to ≤ 6°C; keep from freezing
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
R-33 (VR) [methylphosphonothioic acid, S-[2-(diethylamino)ethyl]O-2-methylpropyl ester]
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-12/653 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap containers with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
R-33 (VR) [methylphosphonothioic acid, S-[2-(diethylamino)ethyl]O-2-methylpropyl ester]
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-12/653 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap containers with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
R-33 (VR) [methylphosphonothioic acid, S-[2-(diethylamino)ethyl]O-2-methylpropyl ester]
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-12/653 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Cool to ≤ 6°C; keep from freezing
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Sarin (GB)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/115 (EPA NHSRC)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Cool to ≤ 6°C; keep from freezing
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Sarin (GB)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/115 (EPA NHSRC)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Cool to ≤ 6°C; keep from freezing
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Sarin (GB)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/115 (EPA NHSRC)
[Tier I]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap containers with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Sarin (GB)
|
|---|
| SAM 2017 Method(s) |
TO-17 (EPA ORD)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
1 - 4 L (flow rate = 16 - 67 mL/min)
|
|---|
| Sample Container: |
Stainless steel, 3.5-inch long tubes with a 6-cm sorbent bed and 1/4-inch o.d.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wrap tube in aluminum foil, and place in a clean sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Sarin (GB)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/115 (EPA NHSRC)
[Tier I]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap containers with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Sodium arsenite (analyze as total arsenic)
|
|---|
| SAM 2017 Method(s) |
9102 (NIOSH) / 6010D / 6020B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
Analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Sodium arsenite, solid, 6.1, Poison, UN2027
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Sodium arsenite (analyze as total arsenic)
|
|---|
| SAM 2017 Method(s) |
3050B/3051A / 6010D/6020B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
Analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Sodium arsenite, solid, 6.1, Poison, UN2027
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Sodium arsenite (analyze as total arsenic)
|
|---|
| SAM 2017 Method(s) |
200.7 / 200.8 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
125 mL
|
|---|
| Sample Container: |
Fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
6 months with acidification. Samples must be acidified within 14 days of collection.
|
|---|
| Preservation: |
• Acidify to pH < 2 with HNO3 [If arsenic species are to be determined, remove unpreserved aliquot prior to sample preservation.]
• Acidified samples can be cooled to ≤ 6°C; keep from freezing
If sample collectors are not able to preserve samples in the field (e.g., acid preservatives are not available), the samples may be preserved in the laboratory. If preserved in the laboratory, however, samples must be held for at least 24 hours prior to analysis.
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Sodium arsenite, aqueous solutions, 6.1, Poison, UN1686
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Sodium arsenite (analyze as total arsenic)
|
|---|
| SAM 2017 Method(s) |
3015A / 6010D/6020B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
125 mL
|
|---|
| Sample Container: |
Fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
6 months with acidification. Samples must be acidified within 14 days of collection.
|
|---|
| Preservation: |
• Acidify to pH < 2 with HNO3 [If arsenic species are to be determined, remove unpreserved aliquot prior to sample preservation.]
• Acidified samples can be cooled to ≤ 6°C; keep from freezing
If sample collectors are not able to preserve samples in the field (e.g., acid preservatives are not available), the samples may be preserved in the laboratory. If preserved in the laboratory, however, samples must be held for at least 24 hours prior to analysis.
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Sodium arsenite, aqueous solutions, 6.1, Poison, UN1686
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Sodium arsenite (analyze as total arsenic)
|
|---|
| SAM 2017 Method(s) |
IO-3.1 / IO-3.4/IO-3.5 (EPA ORD)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
Up to 1700 m3
|
|---|
| Sample Container: |
Filter (quartz, silica, or cellulose fiber)
|
|---|
| Holding Time: |
6 months
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Place filter in protective covering. Place protected filter in double plastic bags, and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Sodium arsenite, solid, 6.1, Poison, UN2027
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Sodium azide (analyze as azide ion)
|
|---|
| SAM 2017 Method(s) |
J. of Forensic Sciences (1998) 43(1): 200-202 / 300.1, Rev 1.0 (EPA OW)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Until holding time data are available, analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Sodium azide, 6.1, Poison, UN1687
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Sodium azide (analyze as azide ion)
|
|---|
| SAM 2017 Method(s) |
J. of Forensic Sciences (1998) 43(1): 200-202 / 300.1, Rev 1.0 (EPA OW)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Until holding time data are available, analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Sodium azide, 6.1, Poison, UN1687
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Sodium azide (analyze as azide ion)
|
|---|
| SAM 2017 Method(s) |
J. of Forensic Sciences (1998) 43(1): 200-202 / 300.1, Rev 1.0 (EPA OW)
[Tier II]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Until holding time data are available, analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Sodium azide, 6.1, Poison, UN1687
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Sodium azide (analyze as azide ion)
|
|---|
| SAM 2017 Method(s) |
ID-211 (OSHA)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
5 L (flow rate = 1 L/min)
|
|---|
| Sample Container: |
Filter / Sorbent tube (PVC or quartz filter with silica coated sorbent [150 mg/75 mg])
|
|---|
| Holding Time: |
10 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of sorbent tube clean using a damp, then dry cloth. Cap both ends of the tube with plastic caps. Place tube in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Sodium azide, 6.1, Poison, UN1687
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Sodium azide (analyze as azide ion)
|
|---|
| SAM 2017 Method(s) |
ID-211 (OSHA)
[Tier I]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
10 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Sodium azide, 6.1, Poison, UN1687
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Soman (GD)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/115 (EPA NHSRC)
[Tier I]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap containers with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Soman (GD)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/115 (EPA NHSRC)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Cool to ≤ 6°C; keep from freezing
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Soman (GD)
|
|---|
| SAM 2017 Method(s) |
TO-17 (EPA ORD)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
1 - 4 L (flow rate = 16 - 67 mL/min)
|
|---|
| Sample Container: |
Stainless steel, 3.5-inch long tubes with a 6-cm sorbent bed and 1/4-inch o.d.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wrap tube in aluminum foil, and place in a clean sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Soman (GD)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/115 (EPA NHSRC)
[Tier I]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap containers with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Soman (GD)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/115 (EPA NHSRC)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Cool to ≤ 6°C; keep from freezing
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Strychnine
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Strychnine
|
|---|
| SAM 2017 Method(s) |
3535A / 8270E (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film. Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Strychnine, 6.1, Poison, UN1692
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Strychnine
|
|---|
| SAM 2017 Method(s) |
3535A / 8270E (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
1 L
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film. Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Strychnine, 6.1, Poison, UN1692
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Strychnine
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Strychnine, 6.1, Poison, UN1692
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Strychnine
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Strychnine, 6.1, Poison, UN1692
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Tabun (GA)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-12/653 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Tabun (GA)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-12/653 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap containers with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Tabun (GA)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-12/653 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap containers with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Tabun (GA)
|
|---|
| SAM 2017 Method(s) |
TO-17 (EPA ORD)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
1 - 4 L (flow rate = 16 - 67 mL/min)
|
|---|
| Sample Container: |
Stainless steel, 3.5-inch long tubes with a 6-cm sorbent bed and 1/4-inch o.d.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wrap tube in aluminum foil, and place in a clean sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Tabun (GA)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-12/653 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Tetraethyl pyrophosphate (TEPP)
|
|---|
| SAM 2017 Method(s) |
TO-10A (EPA ORD)
[Tier II]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
240 - 7200 L (flow rate = 1 - 5 L/min)
|
|---|
| Sample Container: |
Sorbent cartridge containing PUF or PUF in combination with other solid sorbent
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Remove PUF cartridge from sampler, wrap with aluminum foil used to store cartridge, and place in a sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Tetraethyl pyrophosphate (TEPP)
|
|---|
| SAM 2017 Method(s) |
3511 / 8270E (EPA SW-846)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Tetraethyl pyrophosphate (TEPP)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool samples to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Tetraethyl pyrophosphate (TEPP)
|
|---|
| SAM 2017 Method(s) |
3511 / 8270E (EPA SW-846)
[Tier II]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, liquid, 6.1, Poison, UN3018
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Tetraethyl pyrophosphate (TEPP)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool samples to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Organophosphorus pesticides, solid, 6.1, Poison, UN2783
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Tetramethylenedisulfo-tetramine (TETS)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
• Cool to ≤ 6°C; keep from freezing
For treated water samples:
Preservatives/dechlorinating agents not required, but the analyte is not affected by the following, if added to address other analytes:
• Sodium sulfite
• 1.6 - 2.0 mg NH4Cl
[Sodium sulfite can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: for a 1-L sample, add 40 - 50 mg sodium sulfite (1.6 - 2 mg/40-mL sample).]
For all other samples:
• Can be adjusted to pH < 2 with 1:1 HCl, but this is not required
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Pesticides, liquid, toxic, n.o.s, 6.1, Poison, UN2902
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Tetramethylenedisulfo-tetramine (TETS)
|
|---|
| SAM 2017 Method(s) |
TO-10A (EPA ORD)
[Tier II]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
240 - 7200 L (flow rate = 1 - 5 L/min)
|
|---|
| Sample Container: |
Sorbent cartridge containing PUF or PUF in combination with other solid sorbent
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Remove PUF cartridge from sampler, wrap with aluminum foil used to store cartridge, and place in a sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Pesticides, solid, toxic, n.o.s, 6.1, Poison, UN2588
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Tetramethylenedisulfo-tetramine (TETS)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Pesticides, solid, toxic, n.o.s, 6.1, Poison, UN2588
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Tetramethylenedisulfo-tetramine (TETS)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Pesticides, solid, toxic, n.o.s, 6.1, Poison, UN2588
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Tetramethylenedisulfo-tetramine (TETS)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/114 (EPA NHSRC)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer screw-cap VOA vial with fluoropolymer-lined septum
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
• Cool to ≤ 6°C; keep from freezing
For treated water samples:
Preservatives/dechlorinating agents not required, but the analyte is not affected by the following, if added to address other analytes:
• Sodium sulfite
• 1.6 - 2.0 mg NH4Cl
[Sodium sulfite can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: for a 1-L sample, add 40 - 50 mg sodium sulfite (1.6 - 2 mg/40-mL sample).]
For all other samples:
• Can be adjusted to pH < 2 with 1:1 HCl, but this is not required
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film (e.g., fluoropolymer-based), and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Pesticides, liquid, toxic, n.o.s, 6.1, Poison, UN2902
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Thallium sulfate (analyze as total thallium)
|
|---|
| SAM 2017 Method(s) |
3015A / 6010D/6020B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
125 mL
|
|---|
| Sample Container: |
Fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
6 months with acidification. Samples must be acidified within 14 days of collection.
|
|---|
| Preservation: |
• Acidify to pH < 2 with HNO3
• Acidified samples can be cooled to ≤ 6°C; keep from freezing
If sample collectors are not able to preserve samples in the field (e.g., acid preservatives are not available), the samples may be preserved in the laboratory. If preserved in the laboratory, however, samples must be held for at least 24 hours prior to analysis.
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Thallium compounds n.o.s, 6.1, Poison, UN1707
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Thallium sulfate (analyze as total thallium)
|
|---|
| SAM 2017 Method(s) |
IO-3.1 / IO-3.4/IO-3.5 (EPA ORD)
[ Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
Up to 1700 m3
|
|---|
| Sample Container: |
Filter (quartz, silica, or cellulose fiber)
|
|---|
| Holding Time: |
6 months
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Place filter in protective covering. Place protected filter in double plastic bags, and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Thallium compounds n.o.s, 6.1, Poison, UN1707
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Thallium sulfate (analyze as total thallium)
|
|---|
| SAM 2017 Method(s) |
9102 (NIOSH) / 6010D / 6020B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
Analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Thallium compounds n.o.s, 6.1, Poison, UN1707
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Thallium sulfate (analyze as total thallium)
|
|---|
| SAM 2017 Method(s) |
200.7 / 200.8 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
125 mL
|
|---|
| Sample Container: |
Fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
6 months with acidification. Samples must be acidified within 14 days of collection.
|
|---|
| Preservation: |
• Acidify to pH < 2 with HNO3
• Acidified samples can be cooled to ≤ 6°C; keep from freezing
If sample collectors are not able to preserve samples in the field (e.g., acid preservatives are not available), the samples may be preserved in the laboratory. If preserved in the laboratory, however, samples must be held for at least 24 hours prior to analysis.
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Thallium compounds n.o.s, 6.1, Poison, UN1707
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Thallium sulfate (analyze as total thallium)
|
|---|
| SAM 2017 Method(s) |
3050B/3051A / 6010D/6020B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
Analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Thallium compounds n.o.s, 6.1, Poison, UN1707
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Thiodiglycol (TDG) (degradation product of HD)
|
|---|
| SAM 2017 Method(s) |
TO-10A (EPA ORD)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
240 - 7200 L (flow rate = 1 - 5 L/min)
|
|---|
| Sample Container: |
Sorbent cartridge containing PUF or PUF in combination with other solid sorbent
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Remove PUF cartridge from sampler, wrap with aluminum foil used to store cartridge, and place in a sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Aviation regulated solid, n.o.s, UN3335
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Thiodiglycol (TDG) (degradation product of HD)
|
|---|
| SAM 2017 Method(s) |
D7598-16 (ASTM)
[Tier III]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
24 hours
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Aviation regulated liquid, n.o.s, UN3334
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Thiodiglycol (TDG) (degradation product of HD)
|
|---|
| SAM 2017 Method(s) |
E2787-11 (ASTM)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Aviation regulated solid, n.o.s, UN3335
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Thiodiglycol (TDG) (degradation product of HD)
|
|---|
| SAM 2017 Method(s) |
E2838-11 (ASTM)
[Tier II]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Aviation regulated solid, n.o.s, UN3335
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Thiodiglycol (TDG) (degradation product of HD)
|
|---|
| SAM 2017 Method(s) |
D7598-16 (ASTM)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
24 hours
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Aviation regulated liquid, n.o.s, UN3334
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Thiofanox
|
|---|
| SAM 2017 Method(s) |
D7645-16 (ASTM)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
• Acidify to pH ≤ 3.8 with glacial acetic acid
• Cool to ≤ 6°C; keep from freezing
• Prior to collection of treated water samples, add 10 mg ascorbic acid to sample container
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Carbamate pesticides, liquid, toxic, 6.1, Poison, UN2992
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Thiofanox
|
|---|
| SAM 2017 Method(s) |
3541 / 3545A (EPA SW-846) / D7645-16 (ASTM)
[Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Until holding time data are available, analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Carbamate pesticides, solid, toxic, 6.1, UN2757
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Thiofanox
|
|---|
| SAM 2017 Method(s) |
538 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
• Prior to collection, add 400 µL of ammonium acetate concentrated stock and 80 µL of concentrated sodium omadine stock to sample container. [If volumes other than 40-mL are collected, the concentration of ammonium acetate and sodium omadine in the sample should be 1.5 g/L and 64 mg/L, respectively.]
• Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Carbamate pesticides, liquid, toxic, 6.1, Poison, UN2992
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Thiofanox
|
|---|
| SAM 2017 Method(s) |
3570 / 8290A Appendix A (EPA SW-846) / D7645-16 (ASTM)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Carbamate pesticides, solid, toxic, 6.1, UN2757
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Thiofanox
|
|---|
| SAM 2017 Method(s) |
5601 (NIOSH)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
240 - 480 L (flow rate = 0.1 - 1.0 L/min)
|
|---|
| Sample Container: |
Filter/solid sorbent tube (OVS-2 tube: 13 mm quartz filter, XAD-2, [270 mg/140 mg])
|
|---|
| Holding Time: |
30 days if frozen; 7 days at room temperature (24°C)
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of sorbent tube clean using a damp, then dry cloth. Cap both ends of the tube with plastic caps. Place tube in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Carbamate pesticides, solid, toxic, 6.1, UN2757
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Titanium tetrachloride (analyze as total titanium)
|
|---|
| SAM 2017 Method(s) |
3051A / 6010D/6020B (EPA SW-846)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth fluoropolymer or glass container with fluoropolymer-lined lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Titanium tetrachloride, 8, Corrosive, UN1838
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Titanium tetrachloride (analyze as total titanium)
|
|---|
| SAM 2017 Method(s) |
3050B/3051A / 6010D/6020B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
Analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Titanium tetrachloride, 8, Corrosive, UN1838
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Titanium tetrachloride (analyze as total titanium)
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Titanium tetrachloride (analyze as total titanium)
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Titanium tetrachloride (analyze as total titanium)
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Triethanolamine (TEA) (degradation product of HN-3)
|
|---|
| SAM 2017 Method(s) |
3509 (NIOSH)
[Tier II]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
0.5 - 300 L (flow rate = 0.5 - 1 L/min)
|
|---|
| Sample Container: |
Impinger (15 mL 2 mM hexanesulfonic acid)
[Impinger contents are transferred into VOA vial for shipping.]
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
21 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of vial clean using a damp, then dry cloth. Seal the vial with non-reactive tape or film, and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Ethanolamine solutions, 8, Corrosive, UN2491
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Triethanolamine (TEA) (degradation product of HN-3)
|
|---|
| SAM 2017 Method(s) |
D7599-16 (ASTM)
[Tier III]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Ethanolamine solutions, 8, Corrosive, UN2491
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Triethanolamine (TEA) (degradation product of HN-3)
|
|---|
| SAM 2017 Method(s) |
D7599-16 (ASTM)
[Tier II]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Ethanolamine solutions, 8, Corrosive, UN2491
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Triethanolamine (TEA) (degradation product of HN-3)
|
|---|
| SAM 2017 Method(s) |
3541 / 3545A (EPA SW-846) / EPA/600/R-11/123 (EPA NHSRC/CDC)
[Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass, fluoropolymer or polypropylene container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Ethanolamine solutions, 8, Corrosive, UN2491
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Triethanolamine (TEA) (degradation product of HN-3)
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-11/123 (EPA NHSRC/CDC)
[Tier II]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth amber glass, fluoropolymer or polypropylene container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
28 days
|
|---|
| Preservation: |
• Cool to ≤ 6°C
• Protect from light
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Ethanolamine solutions, 8, Corrosive, UN2491
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Trimethyl phosphite
|
|---|
| SAM 2017 Method(s) |
TO-10A (EPA ORD)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
240 - 7200 L (flow rate = 1 - 5 L/min)
|
|---|
| Sample Container: |
Sorbent cartridge containing PUF or PUF in combination with other solid sorbent
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Remove PUF cartridge from sampler, wrap with aluminum foil used to store cartridge, and place in a sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Trimethyl phosphite, 3, Flammable, UN2329
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Trimethyl phosphite
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Trimethyl phosphite
|
|---|
| SAM 2017 Method(s) |
NA
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
For the purposes of SAM, this analyte is not considered to be a concern in this sample type due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
|
|---|
| Sample Container: |
NA
|
|---|
| Holding Time: |
NA
|
|---|
| Preservation: |
NA
|
|---|
| Packaging Requirements: |
NA
|
|---|
| Shipping Label: |
NA
|
|---|
| Notes: |
NA
|
|---|
| Analyte: |
Trimethyl phosphite
|
|---|
| SAM 2017 Method(s) |
3541 / 3545A / 8270E (EPA SW-846)
[Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Trimethyl phosphite, 3, Flammable, UN2329
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Trimethyl phosphite
|
|---|
| SAM 2017 Method(s) |
3570 / 8290 Appendix A / 8270E (EPA SW-846)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
14 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Trimethyl phosphite, 3, Flammable, UN2329
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
VE [Phosphonothioic acid, ethyl-, S-(2-(diethylamino)ethyl) O-ethyl ester]
|
|---|
| SAM 2017 Method(s) |
TO-17 (EPA ORD)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
1 - 4 L (flow rate = 16 - 67 mL/min)
|
|---|
| Sample Container: |
Stainless steel, 3.5-inch long tubes with a 6-cm sorbent bed and 1/4-inch o.d.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wrap tube in aluminum foil, and place in a clean sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
VE [Phosphonothioic acid, ethyl-, S-(2-(diethylamino)ethyl) O-ethyl ester]
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/116 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Cool to ≤ 6°C; keep from freezing
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
VE [Phosphonothioic acid, ethyl-, S-(2-(diethylamino)ethyl) O-ethyl ester]
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/116 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
VE [Phosphonothioic acid, ethyl-, S-(2-(diethylamino)ethyl) O-ethyl ester]
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/116 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
VE [Phosphonothioic acid, ethyl-, S-(2-(diethylamino)ethyl) O-ethyl ester]
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/116 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Cool to ≤ 6°C; keep from freezing
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
VG [Phosphonothioic acid, S-(2-(diethylamino)ethyl) O,O-diethyl ester]
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/116 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Cool to ≤ 6°C; keep from freezing
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
VG [Phosphonothioic acid, S-(2-(diethylamino)ethyl) O,O-diethyl ester]
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/116 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
VG [Phosphonothioic acid, S-(2-(diethylamino)ethyl) O,O-diethyl ester]
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/116 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
VG [Phosphonothioic acid, S-(2-(diethylamino)ethyl) O,O-diethyl ester]
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/116 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Cool to ≤ 6°C; keep from freezing
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
VG [Phosphonothioic acid, S-(2-(diethylamino)ethyl) O,O-diethyl ester]
|
|---|
| SAM 2017 Method(s) |
TO-17 (EPA ORD)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
1 - 4 L (flow rate = 16 - 67 mL/min)
|
|---|
| Sample Container: |
Stainless steel, 3.5-inch long tubes with a 6-cm sorbent bed and 1/4-inch o.d.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wrap tube in aluminum foil, and place in a clean sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
VM [Phosphonothioic acid, methyl-,S-(2-(diethylamino)ethyl) O-ethyl ester]
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/116 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Cool to ≤ 6°C; keep from freezing
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
VM [Phosphonothioic acid, methyl-,S-(2-(diethylamino)ethyl) O-ethyl ester]
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/116 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
VM [Phosphonothioic acid, methyl-,S-(2-(diethylamino)ethyl) O-ethyl ester]
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/116 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Cool to ≤ 6°C; keep from freezing
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
VM [Phosphonothioic acid, methyl-,S-(2-(diethylamino)ethyl) O-ethyl ester]
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/116 (EPA NHSRC)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
VM [Phosphonothioic acid, methyl-,S-(2-(diethylamino)ethyl) O-ethyl ester]
|
|---|
| SAM 2017 Method(s) |
TO-17 (EPA ORD)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
1 - 4 L (flow rate = 16 - 67 mL/min)
|
|---|
| Sample Container: |
Stainless steel, 3.5-inch long tubes with a 6-cm sorbent bed and 1/4-inch o.d.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wrap tube in aluminum foil, and place in a clean sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
VX [O-ethyl-S-(2-diisopropylaminoethyl) methyl- phosphonothiolate]
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/116 (EPA NHSRC)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Cool to ≤ 6°C; keep from freezing
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
VX [O-ethyl-S-(2-diisopropylaminoethyl) methyl- phosphonothiolate]
|
|---|
| SAM 2017 Method(s) |
TO-17 (EPA ORD)
[Tier III]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
1 - 4 L (flow rate = 16 - 67 mL/min)
|
|---|
| Sample Container: |
Stainless steel, 3.5-inch long tubes with a 6-cm sorbent bed and 1/4-inch o.d.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wrap tube in aluminum foil, and place in a clean sealed container. Place container in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
VX [O-ethyl-S-(2-diisopropylaminoethyl) methyl- phosphonothiolate]
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/116 (EPA NHSRC)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
40 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
• Cool to ≤ 6°C; keep from freezing
• Add sodium thiosulfate to remove residual chlorine from treated water samples [Sodium thiosulfate can be added either prior to or after sample collection, but before sample preservation. An amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.]
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
VX [O-ethyl-S-(2-diisopropylaminoethyl) methyl- phosphonothiolate]
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/116 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
VX [O-ethyl-S-(2-diisopropylaminoethyl) methyl- phosphonothiolate]
|
|---|
| SAM 2017 Method(s) |
EPA/600/R-16/116 (EPA NHSRC)
[Tier II]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
40 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Wrap container with bubble wrap. Place in gallon plastic (polypropylene or polyethylene) bag with zipper lock and durability to resist punctures, then into metal can before placing in cooler.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Consult laboratory and/or shipping vendor on specifics regarding shipping label. Wipe outer surface of package with a bleach wipe, taking care not to obscure labeling.
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Vanadium pentoxide (analyze as total vanadium)
|
|---|
| SAM 2017 Method(s) |
3015A / 6010D/6020B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
125 mL
|
|---|
| Sample Container: |
Fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
6 months with acidification. Samples must be acidified within 14 days of collection.
|
|---|
| Preservation: |
• Acidify to pH < 2 with HNO3
• Acidified samples can be cooled to ≤ 6°C; keep from freezing
If sample collectors are not able to preserve samples in the field (e.g., acid preservatives are not available), the samples may be preserved in the laboratory. If preserved in the laboratory, however, samples must be held for at least 24 hours prior to analysis.
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Vanadium pentoxide, 6.1, Poison, UN2862
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Vanadium pentoxide (analyze as total vanadium)
|
|---|
| SAM 2017 Method(s) |
9102 (NIOSH) / 6010D / 6020B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
Analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Vanadium pentoxide, 6.1, Poison, UN2862
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Vanadium pentoxide (analyze as total vanadium)
|
|---|
| SAM 2017 Method(s) |
3050B/3051A / 6010D/6020B (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
Analyze immediately/ as soon as possible
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Vanadium pentoxide, 6.1, Poison, UN2862
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Vanadium pentoxide (analyze as total vanadium)
|
|---|
| SAM 2017 Method(s) |
IO-3.1 / IO-3.4/IO-3.5 (EPA ORD)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
Up to 1700 m3
|
|---|
| Sample Container: |
Filter (quartz, silica, or cellulose fiber)
|
|---|
| Holding Time: |
6 months
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Place filter in protective covering. Place protected filter in double plastic bags, and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Vanadium pentoxide, 6.1, Poison, UN2862
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
Vanadium pentoxide (analyze as total vanadium)
|
|---|
| SAM 2017 Method(s) |
200.7 / 200.8 (EPA OW)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
125 mL
|
|---|
| Sample Container: |
Fluoropolymer, plastic or glass container
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
|
|---|
| Holding Time: |
6 months with acidification. Samples must be acidified within 14 days of collection.
|
|---|
| Preservation: |
• Acidify to pH < 2 with HNO3
• Acidified samples can be cooled to ≤ 6°C; keep from freezing
If sample collectors are not able to preserve samples in the field (e.g., acid preservatives are not available), the samples may be preserved in the laboratory. If preserved in the laboratory, however, samples must be held for at least 24 hours prior to analysis.
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Vanadium pentoxide, 6.1, Poison, UN2862
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
White phosphorus
|
|---|
| SAM 2017 Method(s) |
3570 / 8290A Appendix A / 7580 (EPA SW-846)
[Tier III]
|
|---|
| Sample Type: |
Wipes
|
|---|
| Sample Size: |
1 wipe/100 cm2 or 1 wipe/ft2
Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Samples can be held indefinitely if sealed tightly to eliminate moisture loss.
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Phosphorus, white (dry or wetted), 4.2, Spontaneously combustible, 6.1, Poison, UN1381
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
White phosphorus
|
|---|
| SAM 2017 Method(s) |
7905 (NIOSH)
[Tier I]
|
|---|
| Sample Type: |
Air
|
|---|
| Sample Size: |
5 L (at 0.1 mg/m3) - 100 L (flow rate = 0.01 - 0.2 L/min)
|
|---|
| Sample Container: |
Solid sorbent tube (Tenax GC [100 mg/50 mg])
|
|---|
| Holding Time: |
7 days
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of sorbent tube clean using a damp, then dry cloth. Cap tubes with plastic (not rubber) caps. Place tubes in double plastic bags and wrap with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Phosphorus, white (dry or wetted), 4.2, Spontaneously combustible, 6.1, Poison, UN1381
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
White phosphorus
|
|---|
| SAM 2017 Method(s) |
7580 (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Solid
|
|---|
| Sample Size: |
250 mL
Solid samples should be collected into containers without packing.
|
|---|
| Sample Container: |
Wide-mouth amber glass or fluoropolymer container with fluoropolymer-lined septum or lid
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
Samples can be held indefinitely if sealed tightly to eliminate moisture loss
|
|---|
| Preservation: |
Cool to ≤ 6°C
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Phosphorus, white (dry or wetted), 4.2, Spontaneously combustible, 6.1, Poison, UN1381
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
White phosphorus
|
|---|
| SAM 2017 Method(s) |
7580 (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Non-Drinking Water
|
|---|
| Sample Size: |
500 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid; fill to overflowing to eliminate headspace
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
5 days
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Phosphorus, white (dry or wetted), 4.2, Spontaneously combustible, 6.1, Poison, UN1381
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
| Analyte: |
White phosphorus
|
|---|
| SAM 2017 Method(s) |
7580 (EPA SW-846)
[Tier I]
|
|---|
| Sample Type: |
Drinking Water
|
|---|
| Sample Size: |
500 mL
|
|---|
| Sample Container: |
Amber glass or fluoropolymer container with fluoropolymer-lined septum or lid; fill to overflowing to eliminate headspace
Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
|
|---|
| Holding Time: |
5 days
|
|---|
| Preservation: |
Cool to ≤ 6°C; keep from freezing
|
|---|
| Packaging Requirements: |
Wipe outside of container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film (e.g., fluoropolymer-based). Wrap glass containers with bubble wrap.
Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed preservation requirements. If the target analytes are unknown, samples should be maintained at ≤ 6°C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed around, among, and on top of the sample containers.
|
|---|
| Shipping Label: |
Standard carrier shipping label AND Phosphorus, white (dry or wetted), 4.2, Spontaneously combustible, 6.1, Poison, UN1381
|
|---|
| Notes: |
Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301), appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase "Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
• Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
• Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid (49 CFR 173.152)
• Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
• Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
• Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
|
|---|
