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Ground-level Ozone Pollution

Revision to the Regulatory Definition of Volatile Organic Compounds

The most recently issued VOC Exemption Rules are listed below, with links to fact sheets and additional information.  View a complete list of VOC Exemption Rules.

Exclusion of cis-1,1,1,4,4,4-hexafluorobut-2-ene (HFO-1336mzz-Z)

November 16, 2018 - EPA added HFO-1336mzz-Z to the list of compounds excluded from the regulatory definition of volatile organic compounds or VOC. Evidence shows that HFO 1336mzz-Z is negligibly reactive in forming ground-level ozone. This action will allow states to remove regulatory controls on HFO-1336mzz-Z that are part of State Implementation Plans designed to help meet the ground-level ozone standards. HFO-1336mzz-Z is used in a variety of applications as a replacement for foam expansion or blowing agents. Learn More

Exclusion of HFE-347pcf2

July 20, 2016 - EPA added 1,1,2,2-Tetrafluoro-1-(2,2,2-trifluoroethoxy) ethane (also known as HFE-347pcf2; CAS number 406-78-0) to the list of compounds excluded from the regulatory definition of VOC.  Evidence shows that HFE-347pcf2 is negligibly reactive in forming ground-level ozone. This action will allow states to remove regulatory controls on HFE-347pcf2 that are part of State Implementation Plans designed to help meet the ground-level ozone standards. HFE-347pcf2 is used in a variety of applications as a replacement for precision cleaning.  Learn More

Remove Requirements for t-Butyl Acetate (TBAC)

February 25, 2016 - The regulatory definition of VOC excludes t-butyl acetate (also known as tertiary butyl acetate or TBAC; CAS Number: 540-88-5) for purposes of VOC emissions limitations or VOC content requirements on the basis that it makes a negligible contribution to tropospheric ozone formation.  This action removed remaining Clean Air Act volatile organic compound (VOC) requirements for t-Butyl Acetate (TBAC).    Learn More

Exclusion of 2-Amino-2-Methyl-1-Propanol 

March 27, 2014 - EPA added 2-Amino-2-methyl-1-propanol (also known as AMP, CAS124-68-5) to the list of compounds excluded from the regulatory definition of VOC.  Evidence shows that AMP is negligibly reactive in forming ground-level ozone. This action will allow states to remove regulatory controls on AMP that are part of State Implementation Plans designed to help meet the ground-level ozone standards. AMP is used in a variety of applications for pigment dispersion in water-based coatings such as house paints.  Learn More

Exclusion of 2,3,3,3-tetrafluoropropene

October 22, 2013 - EPA added 2,3,3,3-tetrafluoropropene (also known as HFO-1234yf, CAS number 754-12-1) to the list of compounds excluded from the regulatory definition of volatile organic compounds or VOC. Evidence shows that HFO-1234yf negligibly reactive in forming ground-level ozone. This action will allow states to remove regulatory controls on HFO-1234yf that are part of State Implementation Plans designed to help meet the ground-level ozone standards. HFO-1234yf is used in a variety of applications such as automobile air conditioners. Learn More

Exclusion of trans-1-chloro-3,3,3-trifluoroprop-1-ene (Solstice 1233zd(E)) 

August 28, 2013 - EPA added trans-1-chloro-3,3,3-trifluoroprop-1-ene (also known as Solstice 1233zd(E), CAS number 102687-65-0) to the list of compounds excluded from the regulatory definition of volatile organic compounds or VOC. Evidence shows that Solstice 1233zd(E) is negligibly reactive in forming ground-level ozone. This action will allow states to remove regulatory controls on Solstice 1233zd(E) that are part of State Implementation Plans designed to help meet the ground-level ozone standards. Solstice 1233zd(E) is used in a variety of applications including as a solvent in aerosol and non-aerosol applications, as a blowing agent in insulating foams for refrigerators/freezers and hot water heaters and as a refrigerant in commercial chillers and waste heat recovery (Rankin cycle) systems.  Learn More

Exlusion of a Group of Four Hydrofluoropolyethers (HFPEs)  

February 12, 2013 - EPA added a group of four Hydrofluoropolyethers (HFPEs) to the list of compounds excluded from the regulatory definition of VOC.  Evidence shows that these HFPEs are negligibly reactive in forming ground-level ozone. This action will allow states to remove regulatory controls on the four coupounds that are part of State Implementation Plans designed to help meet the ground-level ozone standards.  These compounds are used in a variety of applications as fire suppressants and refrigerants. Learn More